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 Multiple Choice QuestionsMultiple Choice Questions

241.

Reaction of alkyl halides with aromatic compounds in presence of anhydrous AlCl3 is known as:

  • Friedel-Craft's reaction

  • Hofmann degradation

  • Kolbe's synthesis

  • Beckmann rearrangement


242.

Which of the following will not give iodoform test?

  • Isopropyl alcohol

  • Ethanol

  • Ethanal

  • Benzyl alcohol


243.

The dehydration of 2-methyl butanol with conc. H2SO4 gives :

  • 2-methyl butene as major product

  • pentene

  • 2-methyl but-2-ene as major product

  • 2-methyl pent-2-ene


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244.

Which of the following order is true regarding the acidic nature of phenol?

  • Phenol < o-cresol < o-nitrophenol

  • Phenol > o-cresol > o-nitrophenol

  • Phenol < o-cresol > o-nitropheno

  • o-cresol < phenol < o-nitrophenol


D.

o-cresol < phenol < o-nitrophenol

Presence of electron releasing group like CH3 over benzene nucleus destabilises the phenoxide ion, thus decreases the acidity of phenol where as presence of electron  withdrawing group like NO2 stabilises the phonoxide ion and thus increases the acidity of phenol, hence order of acidity wll be: O-cresol < phenol < O -nitrophenol.


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245.

Identify the correct statement in the following

  • n-butane and isobutane are functional isomers

  • Propan-1-ol and propan-2-ol are position isomers

  • Dimethyl ether and ethanol are chain isomers

  • Ethanoic acid and methyl methanoate are position isomerase.


246.

In the following sequence of reactions

CH3Br KCN, A H3O- B LiAl/H4

The end product C is

 

  • acetone

  • ethyl alcohol

  • methane

  • acetaldehyde


247.

Which of the following will not give a positive iodoform test ?

  • CH3CH2CHOHCH3

  • CH3CH2CH2COCH3

  • CH3CH2COCH2CH3

  • CH3COC6H5


248.

To distinguish between salicylic acid and phenol one can use :

  • NaHCO3 solution

  • 5% NaOH solution

  • neutral FeCl3

  • bromine water


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249.

Acid catalyzed hydration of alkenes except ethene leads to the formation of

  • mixture of secondary and tertiary alcohols

  • mixture of primary and secondary alcohols

  • secondary or tertiary alcohol

  • primary alcohol


250.

Among the following compounds which can be dehydrated very easily ?

  • CH3CH2CH2CH2CH2OH

  • CH3CH2CH2CH(OH)CH3

  • CH3CH2C||OHCH3CHCH3

  • CH3CH2CH(CH3)CH2CH2OH


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