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 Multiple Choice QuestionsMultiple Choice Questions

71.

Aldol is

  • β-hydroxybutyraldehyde 

  • α-hydroxybutanal

  • β-hydroxypropanal

  • None of the above


72.

On treatment of propanone with dilute Ba(OH)2  the product formed

  • aldol

  • phorone

  • propionaldehyde

  • 4-hydroxy-4-methyl-2-pentanone


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73.

Formation of cyanohydrin from a ketone is an example of

  • electrophilic addition

  • nucleophilic addition

  • nucleophilic substitution

  • electrophilic substitution


B.

nucleophilic addition

(Thus, it is an example of nucleophilic addition because the attacking species is a nucleophile)


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74.

Glycerol on treatment with oxalic acid at 110°C forms

  • formic acid

  • allyl alcohol

  • CO2 and CO

  • acrolein


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75.

The fatty acid which shows reducing property is

  • acetic acid

  • ethanoic acid

  • oxalic acid

  • formic acid


76.

One mole of alkene X on ozonolysis gave one mole of acetaldehyde and one mole of acetone. The IUPAC name of X is

  • 2-methyl-2-butene

  • 2-methyl-1-butene

  • 2-butene

  • 1-butene


77.

What are X and Y in the following reaction sequence?

C2H5OH Cl2XCl2Y

  • C2H5Cl, CH3CHO

  • CH3CHO, CH3CO2H

  • CH3CHO, CCl3CHO

  • C2H5Cl, CCl3CHO


78.

What are A, B, C in the following reactions?

(I) (CH3CO2)2Ca A(II) CH3CO2H Red PHI B(III) 2CH3CO2H P4O10C

  • A B C
    C2H6 CH3COCH3 (CH3CO)2O
  • A B C
    (CH3CO)2O C2H6  CH3COCH3
  • A B C
    CH3COCH3 C2H6  (CH3CO)2O
  • A B C
    CH3COCH3 (CH3CO)2O C2H6

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79.

One per cent composition of an organic compound A is, carbon : 85. 71 % and hydrogen 14.29%. Its vapour density is 14. Consider the following reaction sequence

A Cl2/H2OB (ii) H3O+(i) KCN/ EtOHC

Identify C

  • CH3-CH(OH)-CO2H

  • HO-CH2-CH2-CO2H

  • HO-CH2-CO2H

  • CH3-CH2-CO2H


80.

The synthesis of crotonaldehyde from acetaldehyde is an example of........... reaction.

  • nucleophilic addition

  • elimination

  • electrophilic addition

  • nucleophilic addition-elimination


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