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 Multiple Choice QuestionsMultiple Choice Questions

151.

Aldehydes that do not undergo aldol condensation are

1.propanal

2.Trichloroethane

3. methanal

4. benzaldehyde

  • 3 and 4 only

  • 1,2and 3 only

  • 3 and 4 only

  • 2,3 and 4 only


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152.

Which compound among the following give/s positive iodoform test?
1. Ethanol

2. Ethanal

3. 1-butanol

4. 2-butanol

  • 1,2 and 4

  • 1, 3 and 4

  • 1, 2 and 3

  • 1 and 2


A.

1,2 and 4

Carbonyl compounds having CH3CO-group and alcohols having CH3CH(OH)-group undergo iodoform reaction.

CH3CH2OHethanol + 4I2 + 6NaOH  CHI3Iodoform + HCOONa + 5NaI + 5H2OCH3CH2CHOH-CH32-Butanol + 4I2+6NaOH CHI3iodoform + CH3CH2COONa + 5NaI +5H2OCH3CHO Ethanal+ 3I2 + NaOH  CHI3iodoform + HCOONa + 3HI


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153.

The hydroxyl compound that gives a precipitate immediately when treated with concentrated hydrochloric acid and anhydrous zinc chloride is

  • 3-methyl-2-butanol

  • 3-methyl-1-butanol

  • 1-butanol

  • 2-methyl-2-butanol


154.

The product P in the reaction


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155.

Which set of term correctly identifies the carbohydrate show?

                           

1.Pentose

2. Hexose

3. Aldose

4. Ketose

5. Pyranose

6. Furanose

 

  • 1, 3 and 6

  • 1, 3, and 5

  • 2, 3 and 5

  • 2, 3 and 6


156.

Which of the following is a better reducing agent for the following reduction ?

RCOOH → RCH2OH

  • SnCl2/HCl

  • NaBH4/ ether

  • B2H6/ H3O+

  • H2/ Pd


157.

The IUPAC name of the compound is :

HOOC–CH2–CH(COOH)–CH2-CH2-COOH

  • 2(carboxymethyl)-pentane-1, 5-dioic acid

  • 3-carboxyhexane-1, 6-dioic acid

  • butane-1, 2, 4-tricarboxylic acid

  • 4-carboxyhexane-1, 6-dioic acid


158.

IUPAC name of acraldehyde is :

  • but-3-en-1-al

  • propenyl aldehyde

  • prop-2-en-1-al

  • propanal


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159.

The reagent with which both acetaldehyde and acetophenone react easily are :

  • 2, 4-dinitrophenylhydrazine

  • Fehling's solution

  • Schiff's reagent

  • Tollen's reagent


160.

Aniline first reacts with acetyl chloride producing compound' A'. 'A' reacts with nitric acid/ sulphuric acid mixture and produces compound 'B', which hydrolyses to compound 'C'. What is the identity of 'C' ?

  • Acetanilide

  • p-nitroacetanilide

  • p-nitroaniline

  • Aniline


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