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 Multiple Choice QuestionsMultiple Choice Questions

211.

What is Z in the following reaction sequence?

C6H5NH2 (iii) CO, HCl anhy AlCl3/CuCl(i) NaNO2+ HCl/ 273K, (ii) H3PO2+ H2O Z

  • C6H5CO2H

  • C6H5OH

  • C6H5CHO

  • C6H6


212.

CH3MgBr + CO2 Dryether Y H3O Z . Identify Z from the following.

  • Ethyl acetate

  • Acetic acid

  • Propanoic acid

  • Methyl acetate.


213.

In which of the following reactions, the product is not correct?

  • CH3CHO LiAlH4 CH3CH2OH

  • CH3COCH3 HClZn-Hg CH3(OH)2CH3

  • CH3CH2CHO (ii) KOH, ethylene glycol/ (i) H2N-NH2 CH3CH2CH3

  • CH3CH2CHO KMnO4 CH3CH2COOH


214.

Identify the name of the following reaction:

  • Gattermann Koch reaction

  • Gattermann reaction

  • Stephen reaction

  • Etard reaction


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215.

What is C in the following sequence of reaction?

CH3OH PCl3 A KCN B Hydrolysis C

  • CH3CH2OH

  • CH3CHO

  • CH3COOH

  • HOCH2-CH2OH


216.

What are X and Y in the following reactions?


217.

What is Z in the followmg sequence of reactions?

 

  • —CO—CH3

  • —CO—Cl

  • —CH3

  • —CH2—CH3


218.

What are X and Y in the following reactions?

CH2O (ii) H3O+(i) X CH3(CH2)2CH2OHY (ii) H3O+(i) C2H5MgBr CH3CH2C(CH3)2OH

  • X Y
    CH3-CH(CH3)-MgBr C2H5COCH3
  • X Y
    CH3CH2CH2MgBr CH3-CO-CH3
  • X Y
    (CH3)3CMgBr CH3-CO-CH3
  • X Y
    CH3-CH2-MgBr CH3CH2CHO

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219.

The increasing order of acidity of the following carboxylic acids is

  I          II          III       IV

  • III < IV < II < I

  • II < III < II < I

  • I < II < IV < III

  • III < IV < I < II


D.

III < IV < I < II

(i) -NO2 group show -I effect thus increase the acidic nature.

(ii) -OCHand CH3 d CH, are electron donating groups, thus decreases the acidic nature, but -OCH3 will decrease acidic nature more than of -CH3 group.
Hence, correct order is III < IV < I < II.

 


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220.

Which of the following does not contain -COOH group?

  • Citric acid

  • Lactic acid

  • Malanie acid

  • Picric acid


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