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 Multiple Choice QuestionsMultiple Choice Questions

381.

Which one of the following will most readily be dehydrated in acidic medium?

  • CH3—CO—CH2—CH(OH)—CH3

  • CH3—CHOH—CH2—CH2—CH3

  • CH3—COCHOH—CH2—CH3

  • CH3—CO—CH2—CH2—CHOH—CH3


382.

In a Cannizzaro reaction, the intermediate that will be least hydride donor is


383.

In the reaction, CHCl3 + 4OH- → HCOO- + 3Cl- + 2H2O the intermediate species formed is/ are

  • CCl2

  • CCl3-

  • Both (a) and (b)

  • None of the above


384.

When Lunar caustic reacts with acetylene gas, it yields

  • Ag2O

  • AgCOOH

  • Ag2C2

  • Ag


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385.

Product P in the above reaction is


386.

The structure of carboxylate ion is best represented as


387.

. In the above reaction, P and Q respectively are


388.

Benzaldehyde reacts with CH3NH2 forming

  • Schiff's base

  • Hofmann base

  • Saytzeff base

  • None of these


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389.

Consider the following compounds

Friedel-Crafts acylation can be used to obtain:

  • II, III, IV

  • I, II, IV

  • I, II, III

  • I, III, IV


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390.

Which one of the following will be reactive for Perkin condensation ?

  • C6H5-CHO


C.

This reaction occurs between an aromatic aldehyde and an aliphatic anhydride havng atleast two α-H atoms. Electron attracting groups attached to the ring increases the efficiency of Perkin condensation while electron releasing groups (electron donating group) decreases the efficiency of Perkin's reaction.

Hence,  is the most reactive towards perkin's condensation.


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