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 Multiple Choice QuestionsMultiple Choice Questions

41.

The order of equivalent conductances at infinite dilution for LiCl, NaCl and KCl is

  • LiCl > NaCl > KCl

  • KCl > NaCl > LiCl

  • NaCl > KCl > LiCl

  • LiCl > KCl > NaCl


42.

Compound X is tested and the results are shown in the table.

Test Result
Aqueous sodium hydroxide is added, then heated gently. Gas given off which turns damp red litmus paper blue
Dilute hydrochloric acid is added. Effervescence, gas given off which turns lime water milky and acidified K2Cr2O7, paper green.

Which ions are present in compound X?

  • Ammonium ions and sulphite ions

  • Ammonium ions and carbonate ions

  • Sodium ions and carbonate ions

  • Ammonium ions and sulphate ions


43.

Sulphuryl chloride (SO2Cl2) reacts with white phosphorus (P4) to give

  • PCl5, SO2

  • OPCl3, SOCl2

  • PCl5, SO2, S2Cl2

  • OPCl3, SO2, S2Cl2


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44.

Ionisation potential values of noble gases decrease down the group with increase in atomic size. Xenon forms binary fluorides by the direct reaction of elements. Identify the correct statement(s) from below.

  • Only the heavier noble gases form such compounds

  • It happens because the noble gases have higher ionisation energies

  • It happens because the compounds are formed with electronegative ligands

  • Octet of electrons provide the stable arrangements 


A.

Only the heavier noble gases form such compounds

C.

It happens because the compounds are formed with electronegative ligands

Ionisation potential values of noble gases decrease down the group with increase in atomic size. Xenon forms binary fluorides by the direct reaction of elements.

The reason is that only the heavier noble gases form such compounds. Octet of electrons provide the stable arrangements but this statement is not very much valid in cases of higher element which can be ionised easily due to large distance between nucleus and valence electrons.


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45.

If Cl2 is passed through hot aqueous NaOH, the products formed have Cl in different oxidation states. These are indicated as

  • -1 and +1

  • -1and +5

  • +1 and +5

  • -1and +3


46.

The hydrides of the first elements in groups 15-17, namely NH3, H2O and HF respectively show abnormally high values for melting and boiling points. This is due to

  • small size of N, O and F

  • the ability to form extensive intermolecular H-bonding

  • the ability to form extensive intramolecular H-bonding

  • effective van der Waals' interaction


47.

Among the following observations, the correct one that differentiates between SO32- and SO42- is

  • both form precipitate with BaCl2,SO32- dissolves in HCl but SO42- does not.

  • SO32- forms precipitate with BaCl2,SO42- does not.

  • SO42-   forms precipitate with BaCl2, SO32- does not

  • both form precipitate with BaCl2, SO42- dissolves in HCl but SO32- does not.


48.

'Sulphan' is

  • a mixture of SO3 and H2SO5

  • 100% conc. H2SO4

  • a mixture of gypsum and conc. H2SO4

  • 100% oleum (a mixture of 100% SO3 in 100% H2SO4)


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49.

On heating, chloric acid decomposes to

  • HClO4, Cl2, O2 and H2O

  • HClO2, Cl2, O2 and H2O

  • HClO, Cl2O and H2O2

  • HCl, HClO, Cl2O and H2O


50.

The number of acidic protons in H3PO3 are

  • 0

  • 1

  • 2

  • 3


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