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 Multiple Choice QuestionsMultiple Choice Questions

131.

Chlorine atom, in its third excited state, reacts with fluorine to form a compound X. The formula and shape of X are :

  • ClF5,  pentagonal

  • ClF4, tetrahedral

  • ClF4, pentagonal bipyramidal

  • ClF7, pentagonal bipyramidal


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132.

In Fischer-Ringe's method of separation of nobles gas mixture from air ....... is used

  • 90% CaC2 + 10% CaCl2

  • coconut charcoal

  • soda lime + potash solution

  • 90% CaCO3 + 10% urea


A.

90% CaC2 + 10% CaCl2

In Fischer Ringe's method, airfree from moisture and CO2 is passed over a heated mixture (800°C) of 90% CaC2 + 10% CaCl2 in an iron tube, when following reactions take place.

  CaC2 + N2   800°C CaCN2 + C 2C + O  2COC + O2  CO22CaC2 + 3CO2  2CaCO3 + 5CCuO + CO  Cu + CO2

CO2 gas is now absorbed by KOH solution. Thus a mixture of inert gases is obtained.


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133.

In the Dewar's method of separation of noble gases, the mixture of noble gases is kept in contact with coconut charcoal at 173 K. Which one of the following gaseous mixtures is not adsorbed on to the charcoal?

  • Ar, Kr

  • Xe, Ar

  • He, Ne

  • Xe, Kr


134.

The chemical formula of 'tear gas' is

  • COCl2

  • CO2

  • Cl2

  • CCl3NO2


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135.

Which of the following is not correct?

  • Iodine oxidises sodium thiosulphate to sodium tetrathionate

  • Sodium thiousulphate is soluble in water

  • Ozone is used to identify the presence of unsaturation in alkenes

  • Sodium thiosulphate reacts with iodine to form sodium sulphate


136.

Which one of the following pairs of reactants does not form oxygen when they react with each other?

  • F2, NaOH solution (hot, conc.)

  • F2, H2O

  • Cl2, NaOH solution (cold, dilute)

  • CaOCl2, H2SO4 (dilute, small amount)


137.

What is the correct order of occurrence (% by weight) in air of Ne, Ar and Kr ?

  • Ne > Ar > Kr

  • Ar > Ne > Kr

  • Ar > Kr > Ne

  • Ne > Kr > Ar


138.

Hydrolysis of NCl3 gives NH3 and X. Which of the following is X?

  • HClO4

  • HClO3

  • HOCl

  • HClO2


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139.

What are the metal ions present in carnallite?

  • Mg, K

  • Al, Na

  • Na, Mg

  • Zn, Mg


140.

Which of the following is not a peroxy acid ?

  • Perphosphoric acid

  • Pernitric acid

  • Perdisulphuric acid

  • Perchloric acid


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