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 Multiple Choice QuestionsMultiple Choice Questions

171.

The molecular interactions responsible for hydrogen bonding in  HF

  • ion-induced dipole

  • dipole-dipole

  • dipole- induced dipole

  • ion-dipole


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172.

Assertion (A) : AlCl3 exists as a dimer through halogen bridged bonds.

Reason (R) : AlCl3 gets stability by accepting electrons from the bridged halogen.

  • Both (A) and (R) are true and (R) is the correct explanation of (A).

  • Both (A) and (R) are true but (R) is not the correct explanation of (A).

  • (A) is true, but (H) is false.

  • (A) is false, but (R) is true.


A.

Both (A) and (R) are true and (R) is the correct explanation of (A).

AlCl3 exists as a dimer through halogen bridged bonds. It is an electron deficient species. In order to complete the octet of aluminium, the molecule dimerises to form Al2Cl6 in which electrons are added to aluminium octet through coordinate bond by chlorine atom.

Al2Cl6 forms from two AlC3 molecules.


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173.

Which of the following statements regarding sulphur is not correct?

  • At about 1000 K, it mainly consists of S, molecules.

  • The oxidation state of sulphur is never less than + 4 in its compounds.

  • S2 molecule is paramagnetic.

  • Rhombic sulphur is readily soluble in CS2.


174.

Which of the following forms holes in the ozone layer?

  • CO

  • SO2

  • CO2

  • CF2Cl2


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175.

To prepare XeF6. Xe and F2 are mixed at 573 K and 60-70 bar in the ratio of

  • 20:1

  • 1:5

  • 5:1

  • 1:20


176.

In which of the following reactions, hydrogen is liberated?

(i) Al(s) + HCl(aq)  (ii) Al (s) +NaOH(aq)(iii) NaBH4 + I2 

  • i, ii

  • ii, iii

  • i,iii

  • i, ii, iii


177.

Two oxides of an non-metal X contain 50% and 40% of non-metal respectively. If the formula of the first oxide is XO2. Then the formula of second oxide is

  • X2O3

  • X2O5

  • XO3

  • X2O


178.

S + Conc. H2SO4 → X + Y 

Here X is a gas and Y is a liquid and both are triatomic molecules. The number of electron lone pairs present on the central atoms of X and Y are respectively.

  • 2,1

  • 1,0

  • 1,2

  • 2,2


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179.

Which of the following is used in estimation of carbon monoxide?

  • I2O4

  • BrO3

  • Cl2O7

  • I2O5


180.

Which one ofthe following statements is not correct?

  • In CO2 molecule, carbon hybridisation is sp

  • Fullerenes are made by heating graphite in an electric are in the presence of argon gas

  • Both [SiF6]2- and [SiCl6]2- ions are known

  • In CO molecule, there are one 'sigma' and two "pi" bonds


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