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Gujarati JEE Chemistry : રેડોક્ષ પ્રક્રિયા અને વિદ્યુતરસાયણ

Multiple Choice Questions

31. bold Co subscript bold left parenthesis bold s bold right parenthesis end subscript bold space bold plus bold space bold 2 bold Ag to the power of bold 2 subscript bold left parenthesis bold aq bold right parenthesis end subscript bold space bold rightwards harpoon over leftwards harpoon bold space bold Co to the power of bold 2 subscript bold left parenthesis bold aq bold right parenthesis end subscript bold space bold plus bold space bold 2 bold Ag subscript bold left parenthesis bold s bold right parenthesis end subscriptપ્રક્રિયાનો bold E to the power of bold 0 subscript bold Cell bold space bold equals bold space bold 1 bold. bold 08 bold space bold V છે. જો Co2(aq) નું સાંદ્વણ બમનું કરવામાં આવે, તો E0Cell માં શું ફેરફાર થાય ?
  • બમણો થાય.

  • કોઈ ફેરફાર ના થાય.

  • અડધો થાય.

  • બમણાં કરતાં થોડો ઓછો વધે.


32.

જો  bold E subscript bold Zn to the power of bold 2 bold plus bold left parenthesis bold XM bold right parenthesis bold vertical line bold Zn end exponent end subscript bold space bold less than bold space bold E to the power of bold 0 subscript bold Zn to the power of bold 2 bold plus end exponent bold vertical line bold Zn end subscript હોય, તો xની કિંમત કઈ શક્ય છે?

  • 1.2 M

  • 1.0 M

  • 0.2 M

  • નક્કી ના થઈ શકે.


33. bold Pt bold space bold vertical line bold space bold Br subscript bold 2 bold left parenthesis bold 1 bold right parenthesis end subscript bold space bold vertical line bold space bold Br subscript bold left parenthesis bold C subscript bold 1 bold right parenthesis end subscript superscript bold minus bold space bold vertical line bold vertical line bold space bold Au to the power of bold 3 subscript bold left parenthesis bold C subscript bold 2 bold right parenthesis end subscript bold space bold vertical line bold space bold Au વિદ્યુત રાસાયણિક કોષમાં થતી પ્રક્રિયા માટે n અને Q માટે સાચો વિકલ્પ કયો છે ?
  • straight n space equals space 3 comma space straight Q space equals space fraction numerator 1 over denominator left square bracket Au to the power of 3 plus end exponent right square bracket left square bracket Br to the power of minus right square bracket cubed end fraction
  • straight n space equals space 6 comma space straight Q space equals space left square bracket Au cubed right square bracket squared space left square bracket Br to the power of minus right square bracket to the power of 6
  • straight n space equals space 6 comma space straight Q space equals space fraction numerator left square bracket Au to the power of 3 plus end exponent right square bracket squared left square bracket Br to the power of minus right square bracket to the power of 6 over denominator 1 end fraction
  • bold n bold space bold equals bold space bold 3 bold comma bold space bold Q bold space bold equals bold space bold left square bracket bold Au to the power of bold 3 bold right square bracket bold space bold left square bracket bold Br to the power of bold minus bold right square bracket

34. Zn | Zn2(0.005M) || Ag(0.04M) | Ag કોષ માટે ના મૂલ્યને અનુરૂપ Q ના મૂલ્ય માટે કયો વિક્લ્પ યોગ્ય છે ?
  • n = 4, Q = 0.156M-2

  • n = 2, Q = 1.7677M

  • n = 3, Q = 5.5243 Mblank to the power of bold minus begin inline style bold 3 over bold 2 end style end exponent

  • આપેલ પૈકી એક પણ નહી 


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35.

bold Co bold space bold vertical line bold space bold CO to the power of bold 2 subscript bold left parenthesis bold C subscript bold 1 bold right parenthesis end subscript bold space bold vertical line bold vertical line bold space bold Ag to the power of bold 1 subscript bold left parenthesis bold C subscript bold 2 bold right parenthesis end subscript bold space bold vertical line bold space bold Agવિદ્યુત રાસાયણિક કોષ માટે આપેલ કયું નર્નસ્ટ સમીકરણ સાચું છે ?

  • વિદ્યુત રાસાયણિક કોષ માટે straight E to the power of 0 subscript cell space equals space straight E subscript cell space plus space fraction numerator RT over denominator 2 straight F end fraction times In space fraction numerator left square bracket Co to the power of 2 plus end exponent right square bracket over denominator left square bracket Ag to the power of plus right square bracket squared end fraction

  • straight E to the power of 0 subscript cell space equals space straight E subscript cell space plus space fraction numerator RT over denominator 2 straight F end fraction times space In space fraction numerator left square bracket Co to the power of 2 plus end exponent right square bracket over denominator left square bracket Ag to the power of plus right square bracket squared end fraction

  • straight E to the power of 0 subscript cell space equals space straight E subscript cell space minus space fraction numerator RT over denominator 2 straight F end fraction times In space fraction numerator RT over denominator 2 straight F end fraction times In space fraction numerator left square bracket Co to the power of 2 plus end exponent right square bracket over denominator left square bracket Ag to the power of plus right square bracket squared end fraction

  • straight E to the power of 0 subscript cell space minus space straight E subscript cell space equals space fraction numerator RT over denominator 2 straight F end fraction times space In space fraction numerator left square bracket Ag to the power of plus right square bracket squared over denominator left square bracket Co to the power of 2 plus end exponent right square bracket end fraction


A.

વિદ્યુત રાસાયણિક કોષ માટે straight E to the power of 0 subscript cell space equals space straight E subscript cell space plus space fraction numerator RT over denominator 2 straight F end fraction times In space fraction numerator left square bracket Co to the power of 2 plus end exponent right square bracket over denominator left square bracket Ag to the power of plus right square bracket squared end fraction

B.

straight E to the power of 0 subscript cell space equals space straight E subscript cell space plus space fraction numerator RT over denominator 2 straight F end fraction times space In space fraction numerator left square bracket Co to the power of 2 plus end exponent right square bracket over denominator left square bracket Ag to the power of plus right square bracket squared end fraction

CO space vertical line space CO to the power of 2 plus end exponent subscript left parenthesis straight C subscript 1 right parenthesis end subscript space vertical line vertical line space space Ag to the power of plus subscript left parenthesis straight C subscript 2 right parenthesis end subscript space vertical line space Ag વિદ્યુત રાસાયણિક કોષ માટે થતી પ્રક્રિયાનું સમીકરણ

CO subscript left parenthesis straight s right parenthesis end subscript space plus space 2 Ag to the power of plus subscript left parenthesis aq right parenthesis end subscript space rightwards harpoon over leftwards harpoon with space space space space space space space space space on top space Co to the power of 2 plus end exponent subscript left parenthesis aq right parenthesis end subscript space plus space 2 Ag subscript left parenthesis straight s right parenthesis end subscript માટે n  = 2 અને straight Q space equals space open square brackets Co to the power of 2 plus end exponent close square brackets squared over open square brackets Ag to the power of plus close square brackets squared થાય પણ સમીકરણને 2 વડે ભાગવાથી

1 half space Co left parenthesis straight s right parenthesis space plus space Ag to the power of plus subscript left parenthesis aq right parenthesis end subscript space rightwards harpoon over leftwards harpoon with space space space space space space space space space space on top space 1 half space Co subscript 2 to the power of 2 plus end exponent space plus space Ag subscript left parenthesis straight s right parenthesis end subscript

 

માટે n = 1  અને straight Q space equals space fraction numerator open square brackets Co to the power of 2 plus end exponent close square brackets to the power of bevelled 1 half end exponent over denominator open square brackets Ag to the power of plus close square brackets end fraction થશે.
માટે નર્ન્સ્ટ સમીકરણ straight E subscript cell space equals space straight E subscript cell superscript degree space minus space RT over straight F In space fraction numerator left square bracket Co to the power of 2 plus end exponent right square bracket to the power of bevelled 1 half end exponent over denominator open square brackets Ag to the power of plus close square brackets end fraction

therefore space straight E subscript cell superscript degree space equals space straight E subscript cell space plus space RT over straight F space times space In space fraction numerator open square brackets Co to the power of 2 plus end exponent close square brackets to the power of 1 half end exponent over denominator open square brackets left square bracket Ag to the power of plus close square brackets end fraction

CO space vertical line space CO to the power of 2 plus end exponent subscript left parenthesis straight C subscript 1 right parenthesis end subscript space vertical line vertical line space space Ag to the power of plus subscript left parenthesis straight C subscript 2 right parenthesis end subscript space vertical line space Ag વિદ્યુત રાસાયણિક કોષ માટે થતી પ્રક્રિયાનું સમીકરણ

CO subscript left parenthesis straight s right parenthesis end subscript space plus space 2 Ag to the power of plus subscript left parenthesis aq right parenthesis end subscript space rightwards harpoon over leftwards harpoon with space space space space space space space space space on top space Co to the power of 2 plus end exponent subscript left parenthesis aq right parenthesis end subscript space plus space 2 Ag subscript left parenthesis straight s right parenthesis end subscript માટે n  = 2 અને straight Q space equals space open square brackets Co to the power of 2 plus end exponent close square brackets squared over open square brackets Ag to the power of plus close square brackets squared થાય પણ સમીકરણને 2 વડે ભાગવાથી

1 half space Co left parenthesis straight s right parenthesis space plus space Ag to the power of plus subscript left parenthesis aq right parenthesis end subscript space rightwards harpoon over leftwards harpoon with space space space space space space space space space space on top space 1 half space Co subscript 2 to the power of 2 plus end exponent space plus space Ag subscript left parenthesis straight s right parenthesis end subscript

 

માટે n = 1  અને straight Q space equals space fraction numerator open square brackets Co to the power of 2 plus end exponent close square brackets to the power of bevelled 1 half end exponent over denominator open square brackets Ag to the power of plus close square brackets end fraction થશે.
માટે નર્ન્સ્ટ સમીકરણ straight E subscript cell space equals space straight E subscript cell superscript degree space minus space RT over straight F In space fraction numerator left square bracket Co to the power of 2 plus end exponent right square bracket to the power of bevelled 1 half end exponent over denominator open square brackets Ag to the power of plus close square brackets end fraction

therefore space straight E subscript cell superscript degree space equals space straight E subscript cell space plus space RT over straight F space times space In space fraction numerator open square brackets Co to the power of 2 plus end exponent close square brackets to the power of 1 half end exponent over denominator open square brackets left square bracket Ag to the power of plus close square brackets end fraction


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36.

bold Pt bold space bold vertical line bold space bold Cl subscript bold 2 bold left parenthesis bold g bold. bold 1 bold. bold 0 bold space bold બ ા ર bold right parenthesis end subscript bold space bold vertical line bold space bold Cl to the power of bold minus subscript bold left parenthesis bold 0 bold. bold 5 bold M bold right parenthesis end subscript bold space bold vertical line bold vertical line bold space bold Au to the power of bold 3 subscript bold left parenthesis bold 0 bold. bold 4 bold M bold right parenthesis end subscript bold space bold vertical line bold space bold Au  કોષ માટે Q = 20M-4 હોય, તો n = ..... 

  • n = 4

  • n = 3

  • n = 2

  • n = 6


37. વિદ્યુત રાસાયણિક કોષમાં આપેલમાંથી કયા વિકલ્પ માટે Ecell = E0cell થાય ?
  • બંને અર્ધકોષના દ્વાવણની સાંદ્વતા સમાન હોય ત્યારે જ

  • K = 1 તો જ

  • કોષ-પ્રક્રિયા સંતુલનમાં હોય ત્યારે 

  • આપેલ એક પણ નહી.


38.
25degree સે તાપમાને Fe | Fe2(XM) || Ag || Ag(yM) કોષનો વાસ્તવિક પોટૅન્શિયલ 1.295 V છે. 25degreeસે તાપમાને  Fe2(XM) | Fe નો પોટૅન્શિયલ 0.455 V હોય, તો તાપમાને Ag(yM) | Ag કોષનો પોટૅન્શિયલ કેટલો હશે ?
  • 3.125 V

  • 0.84 V

  • -2.135 V

  • 0.84 V


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39.

25degreeસે તાપમાને bold Pt bold space bold vertical line bold space bold H subscript bold 2 bold left parenthesis bold g bold. bold 1 bold. bold 0 bold space bold બ ા ર bold right parenthesis end subscript bold space bold vertical line bold space bold H subscript bold left parenthesis bold pOH bold space bold minus bold space bold 11 bold right parenthesis end subscript (બાર) અર્ધ-કોષનો ઑક્સિડેશન પોટૅન્શિયલ જણાવો.

  • 0.177 V

  • 0.0282 V

  • 0.616 V

  • 0.649 V


40. વિદ્યુત રાસાયણિક કોષનો પોટૅન્શિયલ કારે શૂન્ય થાય ?
  • ઍનોડનો EOX અને કૅથોડનો Ered સમાન થાય ત્યારે

  • ઍનોડન્નો E0redઅને કૅથોડનો E0red સમાન હોય ત્યારે જ 

  • ઍનોડનો EOX અને કૅથોડનો EOX સમાન હોય ત્યારે જ

  • બંને અર્ધકોષના દ્વાવણની સાંદ્વતા સમાન થાય ત્યારે જ


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