Amines

Short Answer Type

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Show by means of equations how an amide may be converted into an amine containing the same number of carbon atoms.

By reduction an amide can be converted into an amine containing the same number of carbon atoms.

RCONH2 + 4[H] → RCH2NH2 + H2O
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    Show by means of equations how an amide may be converted into an amine containing one carbon atom less than the amide.

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    Long Answer Type

    Draw all possible isomers of a benzene containing compound with molecular formula C7H9N. Write their IUPAC names. Explain their reaction towards nitrous acid.
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    Short Answer Type

    How is benzene diazonium chloride obtained?

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    Why does bromination of aniline, even under very mild conditions give 2, 4, 6- tribromo aniline instantaneously?

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    How would you protect the amino group during the nitration of an aromatic amino compound? Give chemical equations.
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    Write the structure of the products of the following reactions:
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    Why are aryl diazonium ions more stable than alkyl diazonium ions?
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    An organic compound (A) with IMF C4H11N, capable of being resolved into optical isomers gives a base soluble product with benzene sulphonyl chloride. What is the structure and IUPAC name of (A)? What happens when this compound (A) is treated with ethanoyl chloride?

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    Explain what is meant by the 'protection of the amino group'.?

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