Short Answer Type

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For each of the following pairs, state which one is larger in size and why?
(i) Na, Na+     (ii) Br, Br-    (iii) Br, I


(i) Na, Na+ pair. The size of Na atom is greater because the cation i.e. Na+ is formed by the loss of one electron from the atom.

(ii) Br, Br- pair. The size of Br- ion is greater as anion is formed by the gain of one electron by bromine atom.

(iii) Br, I pair. The size of 1 is greater because it comes after Br in the halogen family and atomic size increases down the group.

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Describe the theory associated with the radius of an atom as it loses on electron.
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Long Answer Type

Consider the following species : N3-, O2-, F-, Na+, Mg2+ and Al3+

(a) What is common in them?

(b) Arrange them in the order of increasing ionic radii. 

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In each of the following pairs,  which species has a larger size? Explain.
(i) K or K+ 
(ii) Br or Br
- 
(iii) O
2- or F
(iv) Li+ or Na+ 
(v) P or As
(vi) Na
+ or Mg2+

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What do you understand by iso-electronic ions? In iso-electronic ions, the value of ionic radius decreases with the increase in atomic number. Explain.
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Short Answer Type

Describe the theory associated with the radius of an atom as it gains on electron.
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Give the formula of a species which will be isoelectronic with the following atoms or ions:
(i) Na2+ 
(ii) Cl

(iii) Ca2+ 
(iv) Rb
+.

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Which of the following species will have the largest and the smallest size?
Mg, Mg2+, Al, Al3+.

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Long Answer Type

What do you understand by isoelectronic species? Name a species that will be isoelectronic with each of the following atoms or ions.
(i) F-  (ii) Ar    (iii) Mg2+   (iv) Rb+ 

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Short Answer Type

Arrange the following ions in order of increasing size:
Be2+, Cl-, S2-, Na+, Mg2+, Br-.

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