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Square planar complexes do not show optical isomerism. Why?


The essential requirement for a compound to be optically active is that the compound should not have plane of symmetry in its structure. The tetra coordinated complexes with a square planar geometry contain a plane of symmetry. Therefore it do not show optical isomerism.



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Name the ionisation isomer of [Cr(H2O)5Br]SO4.

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What is the significance of Δ0?

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Give the IUPAC name of [NH4]3 [Co(ONO)6].

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Why does [CoF6]3– give a high spin complex?

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Write IUPAC name of the complex  [Co(NH3)5SCN]Cl2.

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Square planar complexes with coordination number of 4 exhibit geometrical isomerism whereas tetrahedral complexes do not. Why?
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[Cu(CN)4]2+ is more stable complex than [Cu(NH3)4]+. Why?
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Give the name of following complex using IUPAC norms:
[Co(en)2(ONO)Cl]Cl. 

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Write the IUPAC name of [Ni(H2O)6] (ClO4)2.

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