Multiple Choice Questions

Advertisement

In which one of the following pairs the radius of the second species is greater than that of the first?

  • Na, Mg

  • O2-, N3-

  • Li+, Be2+

  • Ba2+, Sr2+


B.

O2-, N3-

Among the given pairs,  O2-and  N3-  both are isoelectronic but differ in the charge possessed by them. As the negative charge increase, the electrons are held less and less tightly by the nucleus, therefore, increase radius from O2- to N3-.


Advertisement

'Hydride Gap' is referred to which region of the Periodic Table ?

  • Groups 3, 4 and 5

  • Groups 5, 6 and 7

  • Groups 4, 5 and 6

  • Groups 7, 8 and 9


The first ionisation energy of oxygen is less than that of nitrogen. Which of the following is the correct reason for this observation?

  • Lesser effective nuclear charge of oxygen than nitrogen.

  • Lesser atomic size of oxygen than nitrogen

  • Greater interelectron repulsion between two electrons in the same p-orbital counter balances the increase in effective nuclear charge on moving from nitrogen to oxygen.

  • Greater effective nuclear charge of oxygen than nitrogen.


Which one of the following oxides is amphoteric ?

  • ZnO

  • MgO

  • CaO

  • CO2


The one electron species having ionization energy of 54.4 eV is :

  • H

  • He+

  • B4+

  • Li2+


Advertisement

Consider the ions : K+, S2-, Cl- and Ca2+. The radii of these ionic species follow the order

  • Ca2+ > K+ > Cl- > S2-

  • Cl- > S2- > K+ > Ca2+

  • S2- > Cl- > K+ > Ca2+

  • Ca2+ > S2- > Cl- > Ca2+


The correct match of contents in Column I with those in Column II is

  Column I   Column II
(A) He (i) High electron affinity
(B) Cl (ii) Most electropositive element
(C) Ca (iii) Strongest reducing agent
(D) Li (iv) Highest ionisation energy
  • A-iv, B-i, C-ii, D-iii

  • A-iii, B-i, C-ii, D-iv

  • A-iv, B-iii, C-ii, D-i

  • A-ii, B-iv, C-i, D-iii


In which of the following the oxidation number of oxygen has been arranged in increasing order?

  • OF2 < KO2 < BaO2 < O3

  • BaO2 < KO2  < O< OF2 

  • BaO2  < O< OF2  < KO2 

  •  KO2  < OF2  < O< BaO2 


The electronic configuration of the element with maximum electron affinity is

  • 1s2, 2s2,2p3

  • 1s2, 2s2,2p5

  • 1s2, 2s2,2p6, 3s2, 3p5

  • 1s2, 2s2,2p6, 3s2, 3p3


Advertisement
<

The lattice enthalpy and hydration enthalpy of four compounds are given below

Compound Lattice enthalpy (in kJ mol-1) Hydration
enthalpy
(in kJ mol-1)
P +780 -920
Q +1012 -812
R +828 -878
S +632 -600

The pair of compound which is soluble in water is

  • P and R

  • Q and R

  • P and Q

  • Rand S


Advertisement