(a) CH3-CH2-CH2-NH2
Propan-1-amine (pri)
b) Propan -2-amine (pri)
(c) CH3-CH2-C2H5
N-methylethanamine (Sec)
(d) N,N-Dimethyl methanamine (tert)
primary amine, (a) Propan-1-amine, and (b) Propan-2-amine will liberate nitrogen gas on treatment with nitrous acid.