Arrange the following:In decreasing order of the pKb values C2H

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 Multiple Choice QuestionsShort Answer Type

201.

Give one chemical test to distinguish between the following pairs of compounds.
Aniline and N — methlyaniline.

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202.

Account for the following:
pKb of aniline is more than that of methylamine.

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203.

Account for the following:
Ethylamine is soluble in water, whereas aniline is not.

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204.

Account for the following:
Methylamine in water reacts with ferric chloride to precipitate ferric hydroxide.

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205. Account for the following:
Although amino group is o- and p-directing for aromatic electrophilic substitution reaction, aniline on nitration gives a substantial amount of m-nitro aniline.
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206. Account for the following:
Aniline does not undergo Friedel Craft's reaction.
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207. Account for the following:
Diazonium ions of aromatic amines are more stable than those of aliphatic amines.
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208. Account for the following:
Gabriel phthalimide synthesis is preferred for the synthesizing amines.
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209.

Arrange the following:
In decreasing order of the pKb values C2H5NH2, C6H5 NHCH3, (C2H5)2NH and C6H5NH2.


(C2H5)2NH > C2H5NH2 > C6H5NHCH3 > C6H5NH2.
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210.

Arrange the following:
In decreasing order of basic strength:
C
6H5NH2, C6HsN(CH3)2, (C2H5)2NH and CH3NH2

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