Explain the following: The amino group in ethylamine is basic whereas that in acetamide is not basic.
In amides the lone pair of electrons on nitrogen atom is delocalised and hence less available for protonation than in amines where no resonance is possible and thus
acetamide is a weaker base than ethylamine.
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306.
Explain the following: Cyclo hexylamine is a stronger base than aniline.
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307.
Describe simple tests for distinguishing: p-Toluidine and benzyl amine
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308.
Describe simple tests for distinguishing: CH3ONHC6H5 and C6H5CONH2
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309.
Describe simple tests for distinguishing: C6HsNH3+Cl- and p-ClC6H4NH2
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310.
Describe simple tests for distinguishing: (CH3)4N+OH and (CH3)2NCH2OH