Consider the following reaction,
Which one of the following statements is true for X ?
(I) It gives propionic acid on hydrolysis
(II) It has an ester functional group
(III) It has a nitrogen linked to ethyl carbon
(IV) It has a cyanide group
IV
III
II
I
When acetamide is hydrolysed by boiling with acid, the product obtained is
acetic acid
ethyl amine
ethanol
acetamide
The correct sequence of base strengths in aqueous solution is :
(CH3)2NH > CH3NH2 > (CH3)3N
(CH3)3N > CH3NH2 >(CH3)2NH
(CH3)3N > CH3NH2 = (CH3)2NH
(CH3)2NH > (CH3)3N > CH3NH2
A.
(CH3)2NH > CH3NH2 > (CH3)3N
The order of base strength of amines in aqueous solution is as:
(CH3)2NH > CH3NH2 > (CH3)3N
Tertiary amine is less basic than primary and secondary amine due to steric effect of three methyl group present on nitrogen atom.
When aqueous solution of benzene diazoniumchloride is boiled, the product formed is:
C6H5CH2OH
C6H6 + N2
C6H5COOH
C6H5OH
Carbylamine reaction is given by aliphatic :
primary amine
secondary amine
tertiary amine
quaternary ammonium salt
An organic compound 'A' having molecular formula C2H3N on reduction gave another compound B, upon treatment with nitrous acid 'B' gave ethyl alcohol. On warming with chloroform and alcoholic KOH, it formed an offensive smelling compound 'C'. The compound 'C' is
CH3CH2NH2
CH3CH2N C
CH3C
CH3CH2.OH
Compound (A) (molecular formula C3H8O) is treated with acidified potassium dichromate to form a product B (molecular formula C3H6O). 'B' forms a shining silver mirror on warming with ammoniacal silver nitrate. 'B' when treated with an aqueous solution of H2NCONHNH2 · HCl and sodium acetate gives a product C'. Identify the structure of 'C