An organic compound 'A' having molecular formula C2H3N on reducti

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 Multiple Choice QuestionsMultiple Choice Questions

471.

Consider the following reaction,

C2H5HCl + AgCN EtOH/H2O X (major)

Which one of the following statements is true for X ?

(I) It gives propionic acid on hydrolysis
(II) It has an ester functional group
(III) It has a nitrogen linked to ethyl carbon
(IV) It has a cyanide group

  • IV

  • III

  • II

  • I


472.

When acetamide is hydrolysed by boiling with acid, the product obtained is

  • acetic acid

  • ethyl amine

  • ethanol

  • acetamide


473.

Which will not go for diazotisation?

  • C6H5NH2

  • C6H5CH2NH2


474.

Urea on slow heating gives :

  • NH2CONHNO2

  • NH2CONHCONH2

  • HCNO

  • NH2CONH2.HNO3


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475.

The correct sequence of base strengths in aqueous solution is :

  • (CH3)2NH > CH3NH2 > (CH3)3N

  • (CH3)3N > CH3NH>(CH3)2NH

  • (CH3)3N > CH3NH2 = (CH3)2NH

  • (CH3)2NH > (CH3)3N > CH3NH2 


476.

When aqueous solution of benzene diazoniumchloride is boiled, the product formed is:

  • C6H5CH2OH

  • C6H+ N2

  • C6H5COOH

  • C6H5OH


477.

Carbylamine reaction is given by aliphatic :

  • primary amine

  • secondary amine

  • tertiary amine

  • quaternary ammonium salt


478.

C6H5CHO  NH3 ?

  • (C6H5CHN)2CH·C6H5

  • C6H5NHCH3

  • C6H5NHCH2

  • C6H5NHC6H5


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479.

An organic compound 'A' having molecular formula C2H3N on reduction gave another compound B, upon treatment with nitrous acid 'B' gave ethyl alcohol. On warming with chloroform and alcoholic KOH, it formed an offensive smelling compound 'C'. The compound 'C' is

  • CH3CH2NH2

  • CH3CH2N= C

  • CH3CN

  • CH3CH2.OH


B.

CH3CH2N= C

(i) Proceed back with known compound C2H5OH

(ii) 1° amine on reaction with HNO2 gives 1° alcoho

         CH3-CNmethyl cyanide (A)  Reduction CH3CH2NH2 Ethanamine (B)HONO CH3CH2OH ethanolCH3CH2NH2(B) CHCl3, KOH  CH3CH2N=Cethyl isocyanide (C) 


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480.

Compound (A) (molecular formula C3H8O) is treated with acidified potassium dichromate to form a product B (molecular formula C3H6O). 'B' forms a shining silver mirror on warming with ammoniacal silver nitrate. 'B' when treated with an aqueous solution of H2NCONHNH2 · HCl and sodium acetate gives a product C'. Identify the structure of 'C

  • CH3CH2CH =NNHCONH2

  • (CH3)2C = NNHCONH2

  • (CH3)2C =NCONHNH2

  • CH3CH2CH= NCONHNH2


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