The following species generates a highly stable radical on exposure to 100 W bulb light. Which one of the following represents this stable radical?
Me2(CN)
H3
Me2C(CN)N=
Which of the following nitro compounds are not soluble in NaOH?
(CH3)3C-NO2
(CH3)2CH-NO2
CH3CH2-NO2
Ph-CH2-NO2
The reaction,
R-CO-R RCONHR + N2 is called
Claisen-Schmidt reaction
Kolbe-Schmidt reaction
Schmidt reaction
Kolbe's reaction
Which of the following compounds will give red colour on Lassaigne test?
NaCNS
NH2CSNH2 (thiourea)
p-NH2C6H4SO3H (p- aminobenzene sulphonic acid)
all of the above
A positive carbylamine test is given by
I. N, N-dimethylaniline
II. 2, 4-dimethylamine
III. N-methyl-o-methylaniline
IV. p-methylbenzyl amine
(II) and (IV)
(I) and (IV)
(II) and (III)
(I) and (II)
A.
(II) and (IV)
Carbylamine or isocyanide test is given by only primary amines, whether they are aliphatic or aromatic.
I, II and III are aromatic but compound IV is an aliphatic amine. Further, compound I is tertiary amine, II and IV are primary amines, thus give positive carbylamine test, whereas compound III is a secondary amine.
The IUPAC name of the following compound is
2-carbamoylhexanal
2-carbamoylhex-3-enal
2-methyl-6-oxohex-3-enamide
6-keto-2-methyl hexamide