A positive carbylamine test is given byI. N, N-dimethylanilineII.

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 Multiple Choice QuestionsMultiple Choice Questions

601.

The following species generates a highly stable radical on exposure to 100 W bulb light. Which one of the following represents this stable radical?

  

  • Me2C°(CN)

  • C°H3

  • C°N

  • Me2C(CN)N=C°


602.

Which of the following nitro compounds are not soluble in NaOH?

  • (CH3)3C-NO2

  • (CH3)2CH-NO2

  • CH3CH2-NO2

  • Ph-CH2-NO2


603.

The reaction,

R-CO-R H2SO4N3H RCONHR + N2 is called

  • Claisen-Schmidt reaction

  • Kolbe-Schmidt reaction

  • Schmidt reaction

  • Kolbe's reaction


604.

Which of the following compounds will give red colour on Lassaigne test?

  • NaCNS

  • NH2CSNH2 (thiourea)

  • p-NH2C6H4SO3H (p- aminobenzene sulphonic acid)

  • all of the above


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605.

A positive carbylamine test is given by

I. N, N-dimethylaniline

II. 2, 4-dimethylamine

III. N-methyl-o-methylaniline

IV. p-methylbenzyl amine

  • (II) and (IV)

  • (I) and (IV)

  • (II) and (III)

  • (I) and (II)


A.

(II) and (IV)

Carbylamine or isocyanide test is given by only primary amines, whether they are aliphatic or aromatic.

I, II and III are aromatic but compound IV is an aliphatic amine. Further, compound I is tertiary amine, II and IV are primary amines, thus give positive carbylamine test, whereas compound III is a secondary amine.


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606.

Wat will be the final product of following reaction sequence?


607.

The IUPAC name of the following compound is

 

  • 2-carbamoylhexanal

  • 2-carbamoylhex-3-enal

  • 2-methyl-6-oxohex-3-enamide

  • 6-keto-2-methyl hexamide


608.

Which one of the following is the correct structure of sulphapyridine?


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609.

Iidentify Z in the following reaction:


610.

H3CCONH2 + Br2 + 4 NaOH  Y + Na2CO3+ 2NaBr + 2H2O

  • H3CCH2NH2

  • H3CNH2

  • H3CCOBr

  • HCONH2


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