The correct order of N-compounds in its decreasing order of oxidation states is
HNO3, NH4Cl, NO, N2
HNO3, NO,NH4Cl, N2
HNO3, NO, N2, NH4Cl
NH4Cl, N2, NO, HNO3
Which of the following compounds can form a zwitter ion?
Aniline
Acetanilide
Glycine
Benzoic acid
C.
Glycine
Amphoteric Nature of Glycine: In aqueous solution, glycine exists as an inner salt or a dipolar ion.
This doubly charged ion is known as a Zwitterion or an ampholyte. Due to formation of the ampholyte, glycine acts both as an acid or a base.
In aqueous solution, Zwitter- ion tends to lose a proton. Hence, if electrolyzed, the negative glycine ion will migrate to anode.
The pH value for the isoelectric point of glycine is 6.0.
Nitration of aniline in strong acidic medium also gives m-nitroaniline because
Inspite of substituents nitro group always goes to only m-position.
In electrophilic substitution reactions amino group is meta directive.
In acidic (strong) medium aniline is present as anilinium ion.
In absence of substituents nitro group always goes to m-position.
The correct order of the basic strength of the following are
I>II>III>IV
IV>II>III>I
III>IV>II>I
III>II>IV>I
Which of the following sodium compound/compound (s) are formed when an organic compound containing both nitrogen and sulphur is fused with sodium?
Cyanide and sulphide
Thiocyanate
Sulphite and Cyanide
Nitrate and sulphide
Which of the following is an example of carbylamine reaction?
2Ph NH2 + CS2 Ph- NCS
R - NH2 + HNO2 R - OH + N2 + HCl
Ph - NH2 + CHCl3 + 3KOH (alc.) ph - NC + 3KCl + 3H2O
Ph2 - NH + HONO Ph2 - N - N O + H2O
C3H9N reacts with Hinsberg reagent and the product is insoluble in alkali but soluble in ether. This nitrogen containing compound is
primary amine
secondary amine
tertiary amine
methyl isocyanide