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 Multiple Choice QuestionsMultiple Choice Questions

681.

Which inorganic compound on heating changes into organic compound ?

  • Ammonium cyanide

  • Sodalime

  • Potassium cyanide

  • Sodamide


682.

The bad odour compound formed by the reaction between chloroform and aniline in the presence of alcoholic KOH :

  • acetylene

  • nitro benzene

  • phenyl isocyanate

  • carbylamine


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683.

The reaction of a primary amine with chloroform and ethanolic solution of KOH is called

  • Hofmann's reaction

  • coupling reaction

  • carbylamine reaction

  • Curtius reaction


C.

carbylamine reaction

In carbylamine reaction, aliphatic and aromatic primary amines on heating with chloroform and ethanolic KOH, form isocyanides or carbylamines which are foul smelling substances.

R - NH2 + CHCl3 + 3KOH (alc.)  R - NC + 3KCl + 3H2O


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684.

Hinsberg reagent is :

  • C6H5SO3H

  • C6H5NO

  • C6H5SO2Cl

  • C6H5N2Cl


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685.

Ethyl amine reacts with nitrous acid to form :

  • C2H5OH

  • C2H5OH , N2 , H2O

  • C2H5N2+Cl-

  • C2H5NHOH , NH3


686.

The reaction of chloroform with alcoholic KOH and p toluidine form :


687.

Which one of the following does not participate in the carbylamine reaction ?

  • KOH

  • Ethanol

  • Chloroform

  • Aniline


688.

Alkyl halides react with Mg in dry ether to form :

  • magnesium halide

  • Grignard's reagent

  • alkene

  • alkyne


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689.

If phthalic acid is treated with NH3 and then it is first heated weakly then strongly, the final product formed is


690.

Which of the following will give carbylamine test?

  • CH3NH2

  • CH3NHCH3

  • CH3N(CH3)CH3

  • CH3CONH2


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