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 Multiple Choice QuestionsMultiple Choice Questions

701.

The compound which on reaction with aqueous nitrous acid at low temperature produces an oily nitrosoamine is

  • methyl amine

  • ethyl amine

  • diethyl amine

  • triethyl amine


702.

Hofmann's bromamide reaction is used to convert :

  • acid to alcohol

  • alcohol to acid

  • amide to amine

  • amine to amide


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703.

Compound A (molecular formula C3H8O) is treated with acidified potassium dichromate to form a product B (molecular formula C3H6O). B forms a shining silver mirror on warming with ammoniacal silver nitrate. B when treated with an aqueous solution of H2NCONHNH2. HCl and sodium acetate gives a product C. Identify the structure of C.

  • CH3CH2CH=NNHCONH2

  • CH3-C(CH3)=NNHCONH2

  • CH3-C(CH3)=NCONHNH2

  • CH3CH2CH=NCONHNH2


A.

CH3CH2CH=NNHCONH2

A is an alchohol and its oxidation product gives Tollen's test.Tollen's reagents is a chemical reagents used to determine the presence of aldehyde, aromatic aldehyde, and alpha-hydroxyl ketone functional group. The reagent consists of a solution of sliver nitrate, ammonia and some sodium hydroxide.

C3H8OA  K2Cr2O7/ H+ C3H6OB amm. AgNO3 Silver mirror

Reaction of B indicates that B is an aldehyde thus B should be C2H5CHO or CH3CH2CHO and therefore C should be CH3CH2CH=NNHCONH2.

CH3CH2CH2OH[A] [O] CH3CH2CHO [B] Silver mirror testCH3CH2COOH + 2Ag

CH3CH2CH2OH + H2NNHCONH2semicarbazide  CH3CH2CH=NNHCONH2semicarbazone [C]


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704.

Which of the following fibres is not made up of polyamides ?

  • Wool

  • Natural silk

  • Artificial silk

  • Nylon


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705.

The high oxidising power offluorine is due to :

  • high electron affinity

  • high heat of dissociation and low heat of hydration

  • high heat of hydration and low heat of dissociation

  • high heat of hydration and high heat of dissociation


706.

Toluene is nitrated and the resulting product is reduced with tin and hydrochloric acid. The product so obtained is diazotised and thenheated with cuprous bromide. The reaction mixture so formed contains

  • mixture of o- and m-bromotoluenes

  • mixture of o- and p-bromotoluenes

  • mixture of o- and p-dibromobenzenes

  • mixture of o- and p-bromoanilines


707.

Identify the 'C' in the reaction :

RNH2 HNO2 A + B + C

  • NH3

  • O2

  • N2

  • CO2


708.

The reaction of an organic compound with ammonia followed by nitration of the product gives a powerful explosive called ROX.The organic compound is

  • phenol

  • toluene

  • glycerine

  • formaldehyde


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709.

CH3Br + KCN (alco.)  X Na + C2H5OHReduction Y

What is Y in the series ?

  • CH3CN

  • C2H5CN

  • C2H5NH2

  • CH3NH2


710.

In the following sequence of the reactions, what is D ?

  • Primary amine

  • An amide

  • Phenyl isocyanate

  • A chain lengthed hydrocarbon


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