What is resonance enthalpy? What is its significance? from Chem

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 Multiple Choice QuestionsShort Answer Type

201.

Which out of the two molecules - OCS and CS2 has a higher dipole moment and why ?

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 Multiple Choice QuestionsLong Answer Type

202.

Discuss the applications (or importance) of dipole moment.

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 Multiple Choice QuestionsShort Answer Type

203.

The molecule of SO2 has a dipole moment. Is the molecule linear or bent? Explain your answer.

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204.

Predict the dipole moment of;
(i) a molecule of the type AX4 having a square planar geometry.
(ii) a molecule of the type AX5 having a trigonal bipyramdial.
(iii) a molecule of the type AX6 having an octahedral geometry.

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205.

Which of the two - NH3 and NF3 has higher dipole moment and why?

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206.

What do you understand by resonance?

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 Multiple Choice QuestionsLong Answer Type

207.

Discuss the resonance in CO2 and O3molecule.

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208.

Write the resonance structures for SO3,   NO2 and NO subscript 3 superscript minus.

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 Multiple Choice QuestionsShort Answer Type

209.

Write the resonance structure for:
(i) Benzene (C6H6)
(ii) Carbonate ion (CO3)

 
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 Multiple Choice QuestionsLong Answer Type

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210.

What is resonance enthalpy? What is its significance?


The actual enthalpy of the molecule (i.e. enthalpy of resonance hybrid) is always found to be less than the enthalpy of any of its contributing structures. This difference in enthalpy is called resonance enthalpy. It is defined as the difference in enthalpy between the enthalpy of the most stable of the contributing structures and the enthalpy of the actual molecule (resonance hybrid).

Resonance enthalpy = Enthalpy of the most stable contributing structure -  enthalpy of resonance hybrid.

Due to the low fo resonance hybrid, it is more stable than any of its contributing structures. In other words, it can be said that resonance hybrid is always more stable because of resonance enthalpy. Larger the resonance enthalpy, more will be the stability of the compound. Also, relative stabilities of two hybrids can be compared in terms of resonance enthalpies.
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