Draw the molecular orbital energy diagram for oxygen molecule (

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 Multiple Choice QuestionsLong Answer Type

231.

Discuss the formation of N2 molecule on the basis of MO theory. Predict its:
(i) Bond order
(ii) Magnetic character.

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232.

Write the stability configuration of straight N subscript 2 superscript plus comma space space straight N subscript 2 superscript minus space space or space space straight N subscript 2 superscript 2 minus end superscript space ions and predict their bond order, stability and magnetic character. 

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233.

Draw the molecular orbital energy diagram for oxygen molecule (O2) and show that:
(i) It has a double bond
(ii) It has paramagnetic character.


Electronic structure of oxygen atom is  Leaving out the 4 electrons in the 1s orbitals of two oxygen atoms constituting the molecule (represented as KK), the molecular orbital energy diagram for remaining 12 electrons of oxygen as molecule is shown:


(i) Electronic configuration:


(ii) Bond order: Here Nb = 8;    Na = 4

The two oxygen atoms in a molecule of oxygen are united through two covalent bonds (i.e.  a double bond).

(iii) Paramagnetic character : Since a molecule of oxygen has two unpaired electrons in the  orbitals, molecular oxygen should be paramagnetic.
 
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234.

Using a molecular orbital diagram, predict the bond order, stability and magnetic character of O2,O2+, and straight O subscript 2 superscript 2 minus end superscript left parenthesis peroxide space ion right parenthesis . Also, write their electronic configurations.

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235.

Discuss the relatives stabilities, bond dissociation energies and bond lengths of O2
space space straight O subscript 2 superscript plus comma space straight O subscript 2 superscript minus space an space straight O subscript 2 superscript 2 minus end superscript species. 
      

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236.

Is the bond order in superoxide ion more or less than in peroxide ion? Explain on the basis of MO theory.

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 Multiple Choice QuestionsShort Answer Type

237.

Calculate the bond order of He subscript 2 superscript plus comma space straight O subscript 2 superscript minus comma space straight O subscript 2 superscript plus molecular ions. 

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238.

Using bond order show that N2 would be expected to have a triple bond, F2 a single bond and Ne2 no bond.

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239.

Show that N2 molecule has a greater bond dissociation energy than N-2 where O2 has lower bond dissociation energy than O+2.

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240.

Which of the following has higher bond dissociation energy and why?
(i) N+  (ii) O+

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