Discuss the formation of N2 molecule on the basis of MO theory. Predict its:
(i) Bond order
(ii) Magnetic character.
Write the stability configuration of and predict their bond order, stability and magnetic character.
Draw the molecular orbital energy diagram for oxygen molecule (O2) and show that:
(i) It has a double bond
(ii) It has paramagnetic character.
Using a molecular orbital diagram, predict the bond order, stability and magnetic character of O2–,O2+, and . Also, write their electronic configurations.
Discuss the relatives stabilities, bond dissociation energies and bond lengths of O2,
species.
Is the bond order in superoxide ion more or less than in peroxide ion? Explain on the basis of MO theory.
The MO electronic configuration of superoxide ion is
Here
The M.O. electronic configuration of peroxide ion is
So, the bond order in superoxide ion is more than in peroxide ion.
Using bond order show that N2 would be expected to have a triple bond, F2 a single bond and Ne2 no bond.
Show that N2 molecule has a greater bond dissociation energy than N-2 where O2 has lower bond dissociation energy than O+2.