Which of the following has the highest bond order? from Chemistr

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521.

Which of the following has the highest bond order?

  • N2

  • O2

  • He2

  • H2


A.

N2

Molecular orbital configuration ofN2 = 14e-= σ1s2, σ*1s2, σ2s2, σ*2s2,σ2px2, π2py2, π2pz2Bond order =Nb- Na2= 10-42=3similarly for O2 molecule, bond order = 2For He2 molecule, bond order = 0For H2 molecule bond oeder = 1So, N2 has highest bond order.


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522.

During the formation of a chemical bond

  • electron-electron repulsion becomes more than the nucleus-electron attraction.

  • energy of the system does not change.

  • energy increases

  • energy decreases


523.

Which of the following is diamagnetic?

  • H2+

  • O2

  • Li2

  • He2+


524.

In acetylene molecule, between the carbon atoms there are

  • three pi bonds

  • one sigma and two pi bonds

  • two sigma and one pi bonds

  • three sigma bonds


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525.

The number of nodal planes present in σ* antibonding orbitals is

  • 1

  • 2

  • 0

  • 3


526.

The overlapping of orbitals in benzene is of the type

  • sp-sp

  • p-p

  • sp2-sp2

  • sp3-sp3


527.

The calculated bond order of superoxide ion O2- is

  • 2.5

  • 2

  • 1.5

  • 1


528.

In the ionic equation

-BiO3- + 6H+ + xe- → Bi3+ + 3H2O , the value of x is

  • 6

  • 2

  • 4

  • 3


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529.

Mesomeric effect involves delocalisation of

  • pi electrons

  • sigma electron

  • protons

  • None of these


530.

Angle strain in cyclopropane is

  • 24°44'

  • 9°44'

  • 44'

  • -5°16'


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