Consider the following ions:(i) Ni2+   (ii) Co2+ 

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 Multiple Choice QuestionsMultiple Choice Questions

591.

The bond angle is smallest in

  • H2O

  • H2S

  • BeCl2

  • N2O


592.

Which of the following shell, form an outer octahedral complex?

  • d4

  • d8

  • d6

  • None of these


593.

Valence bond theory of metallic bond was given by

  • Dalton

  • Drudel

  • Fajan

  • Pauling 


594.

The calculated bond order in O2- ions is

  • 1

  • 1.5

  • 2

  • 2.5


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595.

Which combination of atoms can form a polar covalent bond ?

  • H and N

  • H and Br

  • N and N

  • Na and Br


596.

The bond length of H2+, H2- and H2 are in the following order

  • H2+ > H2 > H2-

  • H2H2+ > H2-

  • H2- > H2 > H2+

  • H2- > H2+ > H2


597.

The correct order of bond length is

  • b > a > c > d

  • a > b > c > d

  • d > c > b > a

  • c > d > b > a


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598.

Consider the following ions:

(i) Ni2+   (ii) Co2+  (iii) Cr2+   (iv) Fe3+

(Given, at. no. Cr = 24, Fe = 26, Co = 27, Ni = 28)

The correct order of magnetic moment of these ions is

  • (i) < (ii) < (iii) < (iv)

  • (iv) < (ii) < (iii) < (i)

  • (i) < (iii) < (ii) < (iv)

  • (iii) < (iv) < (ii) < (i)


A.

(i) < (ii) < (iii) < (iv)

Magnetic moment, μ = n(n + 2) BM

where, n = number of unpaired electrons

Higher the number of unpaired electrons, more the value of μ.

The electronic configuration of given species are-

Ni2+ = [Ar]3d8 (two unpaired electrons)

Co2+ = [Ar]3d7 (three unpaired electrons)

Cr2+ = [Ar]3d4 (four unpaired electrons)

Fe3+ = [Ar]3d5 (five unpaired electrons)

Thus, the order of magnetic moment is-

Ni2+(i) < Co2+(ii) < Cr2+(iii) < Fe3+(iv)


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599.

Geometry of methyl free radical is

  • pyramidal

  • planar

  • tetrahedral

  • linear


600.

The electron configuration of the oxide ion is much most similar to the electron configuration of the

  • sulphide ion

  • nitride ion

  • oxygen atom

  • nitrogen atom


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