The ONO angle is maximum in from Chemistry Chemical Bonding and

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851.

The statement true for N3- is

  • it has a non-linear structure

  • it is called pseudohalogen

  • the formal oxidation state of nitrogen in this anion is -1

  • it is isoelectronic with NO2


852.

Which of the following molecule has highest bond energy ?

  • F-F

  • N-N

  • C-C

  • O-O


853.

Shape of O2F2 is similar to that of

  • C2F2

  • H2O2

  • H2F2

  • C2H2


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854.

The ONO angle is maximum in

  • NO3-

  • NO2-

  • NO2

  • NO2+


D.

NO2+

The nitrate ion has three resonance structure, with the double bond on a different oxygen for each. In all resonance structures the nitrogen has three bonds, therefore, its hybridisation is sp2. Each of the oxygen atoms also has sp2 hybridisation, since the hybridisation is determined by the resonance structure with the double bond, where the oxygen has a double bond and two lone pairs.

The actual geometry of the polyatomic ion is trigonal planar with bond angles of 120°,

NO2-:18 electrons; ideal geometry trigonal planar, sp2 with bond angle of 116°.

NO2 : 17 electrons, ideal geometry trigonal planar; sp2 with bond angle of 134°.

NO2+: 16 electrons; ideal geometry linear ; sp with bond angle of 180°,

               O....=N+=O....


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855.

The number of σ and π bonds present in pent-4-ene, I-yne is :

  • 10 , 3

  • 4 , 9

  • 3 , 10

  • 9 , 4


856.

The dipole moment is the highest for

  • trans-2-butene

  • 1,3-dimethylbenzene

  • acetophenone

  • ethanol.


857.

Which of the following are arranged in the decreasing order of dipole moment?

  • CH3Cl, CH3Br, CH3F

  • CH3Br, CH3Cl, CH3F

  • CH3Cl, CH3Br, CH3F

  • CH3Br, CH3F, CH3Cl


858.

Assertion : The free gaseous Cr atom has six unpaired electrons.

Reason: Half-filled s orbital has greater stability.

  • If both assertion and reason are true and reason is the correct explanation of assertion

  • If both assertion and reason are true but reason is not the correct explanation of assertion

  • If assertion is true but reason is false

  • If both assertion and reason are false.


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859.

Assertion : All F- S -F angle in SF4 is greater than 90° but less than 180°.

Reason : The lone pair-bond pair repulsion is weaker than bond pair-bond pair repulsion.

  • If both assertion and reason are true and reason is the correct explanation of assertion

  • If both assertion and reason are true but reason is not the correct explanation of assertion

  • If assertion is true but reason is false

  • If both assertion and reason are false.


860.

Which of the following compounds possesses the C-H bond with the lowest bond dissociation energy?

  • Toluene

  • Benzene

  • n-Pentane

  • 2,2-Dimethylpropane


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