81.Which of the reactions slow or fast, will have higher activation energy?
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82.What information can we had from the statement that the energy of activation of a reaction is zero?
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83.Define collision frequency factor.
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84.For the reaction H2 + I2 → 2HI, What is the molecularity of the reaction?
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85.Define the term ‘order of reaction’ for chemical reactions.
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86.The decomposition of dimethyl ether leads to the formation of CH4, H2 and CO and the rate is given by Rate = k[CH3OCH3]3/2 The rate of reaction is followed by increase in pressure in a closed vessel, so the rate can also be expressed in terms of the partial pressure of dimethyl ether, i.e., Rate = k pCH3O CH3 3/2. If the pressure is measured in bar and time in minutes, then what are the units of rate and rate constants?
87.List the factors on which the rate of a chemical reaction depends.
The various factors which affect the rate of chemical reactions are: (i) Concentration of reactants (ii) Temperature of reaction (iii) Presence of catalyst (iv) Nature of reactants (v) Surface area (vi) Exposure to radiations.
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Long Answer Type
88.From the rate expression for the following reactions, determine their order of reaction and the dimensions of the rate constants (i) 3NO(g) → N2O (g) Rate = k[NO]2 (ii) H2O2 (aq) + 3I– (aq) + 2H+ → 2H2O (l) + I-3 Rate = k[H2O2][I-] (iii) CH3CHO (g) → CH4 (g) + CO(g) Rate = k [CH3CHO]3/2 (iv) C2H5Cl (g) → C2H4 (g) + HCl (g) Rate = k [C2H5Cl]
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89.A reaction is second order with respect to a reactant. How is the rate of rection affected if the concentration of the reactant is (i) Doubled (ii) Reduced to 1/2?
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90.A reaction is first order in A and second order in B (i) Write differential rate equation. (ii) How is the rate affected when the concentration of B three times? (iii) How is the rate affected when the concentrations of both A and B are doubled?