If water contains dissolved calcium bicarbonate, out of soaps and synthetic detergents which one will you use for cleaning clothes?
Calcium hydrogen carbonate present in water will furnish Ca2+ ions which cause hardness in water.
calcium ion form insoluble calcium soaps respectively when sodium potassium soaps are dissolved in hard water.
2C17H35COONa --> 2NaCl + (C17H35COO)2Ca
Soap insoluble calcium stearate
Therefore, soaps cannot be used to clean clothes with such water.