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 Multiple Choice QuestionsShort Answer Type

141. Explain why difference in IE, and IE2 values of sodium is more than that of magnesium.
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142.

Energy of an electron in the ground state of the hydrogen atom is -2.18 X 10-18J. Calculate the ionization enthalpy of atomic hydrogen in terms of J mol-1.

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 Multiple Choice QuestionsLong Answer Type

143. Would you expect the second electron gain enthalpy of O as positive, more negative or less negative than the first? Justify your answer.
Or
What are successive electron gain enthalpies? Explain why second or higher electron gain enthalpy will have positive value.
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 Multiple Choice QuestionsShort Answer Type

144.

Discuss in brief the factors which influence the magnitude of electron gain enthalpy.

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145.

How does electron gain enthalpy vary along a group?


The electron gain enthalpy of elements become less negative as we move from top to bottom down a group. This is because on moving down a group, there is the simultaneous increase in atomic size and nuclear charge. However, the effect of the increase in size is greater than the increase in nuclear charge. As a result, the incoming electron feels lesser attraction by the large atom. Consequently, electron gain enthalpy becomes less negative down a group.
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146.

How does electron gain enthalpy vary along a period?

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147.

Why do halogens have very higher value of electron gain enthalpy?

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148.

Why do noble gases have large positive electron gain enthalpies?

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149.

The electron gain enthalpy of fluorine has less negative value than that of chlorine while it is expected to be more. Explain.

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150.

Explain which of the following will have the most negative electron gain enthalpy and which the least negative: P, S, CI, F.

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