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 Multiple Choice QuestionsMultiple Choice Questions

211.

If the ionisation energy and electron affinity of an element are 275 and 86 kcal mol-1 respectively, then the electronegativity of the element on the Mulliken scale is

  • 2.8

  • 0.0

  • 4.0

  • 2.6


212.

Which of the following has the maximum number of unpaired d-electrons?

  • Fe2+

  • Cu+

  • Zn

  • Ni3+


213.

An f-shell containing 6 unpaired electrons can exchange

  • 6 electrons

  • 9 electrons

  • 12 electrons

  • 15 electrons


214.

Among the elements Ca, Mg, P and Cl, the order of increasing atomic radii is

  • Mg< Ca< Cl< P

  • Cl <P <Mg< Ca

  • P <Cl< Ca< Mg

  • Ca <Mg <P < Cl


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215.

Among the following which one has the highest cation of anion size ratio?

  • Csl

  • CsF

  • LiF

  • NaF


B.

CsF

The order of size of given cations is  Li+< Na+< Cs+ and the order of size of given anions is I- > F-. Thus, when the cation is largest and anion is smallest, the cation to anion size ratio is maximum. Hence, cation to anion size ratio is maximum for CsF.


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216.

What is the value of electron gain enthalpy of Na if IE1 of Na = 5.1 eV?

  • -5.1 eV

  • -10.2 eV

  • +2.55 eV

  • +10.2eV


217.

Assertion (A): K, Rb and Cs form superoxides.

Reason (R): The stability of the superoxides increases from 'K' to 'Cs' due to decrease in lattice energy.

The correct answer is

  • Both (A) and (R) are true and (R) is the correct explanation of (A).

  • Both (A) and (R) are true but (R) is not the correct explanation of (A)

  • (A) is true but (R) is not true

  • (A) is not true but (R) is true


218.

Which one of the following order is correct for the first ionisation energies of the elements?

  • B <Be <N < O

  • Be <B <N < O

  • B <Be <O <N

  • B <O <Be <N


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219.

The oxidation number of oxygen in KO3, Na2O2 is

  • 3, 2

  • 1, 0

  • 0, 1

  • -0.33, -1


220.

What is the fuel of atomic pile ?

  • Thorium

  • Sodium

  • Uranium

  • Petroleum


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