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 Multiple Choice QuestionsMultiple Choice Questions

231.

Choose the wrong statement from the following 

  • The 'silver' UK coins are made of Ag/ Ni alloy 

  • TiO2 is used in the pigment industry

  • MnO2 is used in the dry battery cells

  • V2O5 catalyses the oxidation of SO2 in the manufacture of sulphuric acid


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232.

The correct order of first ionisation enthalpies of the following elements is

  • Be > Mg > Ca > Sr > Ra > Ba

  • Ra > Ba > Sr > Ca > Mg > Be

  • Be > Mg > Ca > Sr > Ba > Ra

  • Ra > Sr > Ba > Mg > Ca > Be


A.

Be > Mg > Ca > Sr > Ra > Ba

Ionisation enthalpy decrease on going down the group. So, 

IE ∝ 1size

However, radium has exceptionally higher ionisation enthalpy in Group 2.

The first ionisation enthalpy in kJ mol-1 of alkali metal and alkaline earth metals are as following-

Be = 899; Mg = 737; Ca = 590; Sr = 549; Ra = 509; Ba = 503

Hence, order of ionisation enthalpy is 
Be > Mg > Ca > Sr > Ra > Ba


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233.

The correct discending order of oxidising power of the following is

  • Cr2O72- > MnO4- > VO2+

  • MnO4- > Cr2O72- > VO2+

  • VO2+ > MnO4- > Cr2O72-

  • MnO4- > VO2+ > Cr2O72-


234.

The number of electrons that are involved in the reduction of permanganate to manganese (II) salt, manganate and manganese dioxide respectively are

  • 5, 1, 3

  • 5, 3, 1

  • 2, 7, 1

  • 5, 2, 3


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235.

The ionisation enthalpy of He+ ion is 19.60 10-18 J atom-1. The ionisation enthalpy of Li2+ ion will be

  • 84.2 × 10-18 J atom-1

  • 44.10 × 10-18 J atom-1

  • 63.20 × 10-18 J atom-1

  • 21.20 × 10-18 J atom-1


236.

Among the elements B, Mg, Al and K the correct order of increasing metallic character is

  • B < Al < Mg < K

  • B < Mg < Al < K

  • Mg < B < Al < K

  • Mg < Al < B < K


237.

Which one of the following is an amphoteric oxide?

  • Mn2O7

  • CrO

  • V2O4

  • Cr2O3


238.

Molecules/ ions and their magnetic properties are given below-

Molecule/ Ion Magnetic Property
i. C6H6 1. Antiferromagnetic
ii. CrO2 2. Ferrimagentic
iii. MnO 3. Ferromagnetic
iv. Fe3O4 4. Paramagnetic
v. Fe3+ 5. Diamagnetic

The correctly matched pairs in the above is

  • i - 5; ii - 3; iii - 2; iv - 1; v - 4

  • i - 3; ii - 5; iii - 1; iv - 4; v - 2

  • i - 5; ii - 3; iii - 1; iv - 2; v - 4

  • i - 5; ii - 3; iii - 1; iv - 4; v - 2


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239.

Among the following, the element of highest first ionisation enthalpy is

  • C

  • Ne

  • Be

  • N


240.

Arrange the following in the order of increasing mass (atomic mass O = 16, Cu = 63, N = 14)

I. One atom of oxygen

II. One atom of nitrogen

III. 1 × 10-10 mole of oxygen

IV. 1 × 10-10  mole of copper

  • II < I < III < IV

  • I < II < III < IV

  • III < II < IV < I

  • II < IV < I < III


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