Write down the IUPAC name for each of the following complexe

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 Multiple Choice QuestionsLong Answer Type

181. What is crystal field splitting energy? How does the magnitude of Δ0 decide the actual configuration of d orbitals in a coordination entity?
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182. [Cr(NH3)6)3+ is paramagnetic while [Ni(CN)4]2 – is diamagnetic. Explain why?
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183.

Discuss the nature of bonding in metal carbonyls.

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 Multiple Choice QuestionsShort Answer Type

184.

Give the oxidation state, d-orbital occuptaion and coordination number of the central metal ion in the following complexes:
K3[Co(C2O4)3]

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185.

Give the oxidation state, d-orbital occuptaion and coordination number of the central metal ion in the following complexes:
cis-[Cr(en) 2Cl2]Cl

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186.

Give the oxidation state, d-orbital occuptaion and coordination number of the central metal ion in the following complexes:
(NH4)2[CoF4]

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187.

Give the oxidation state, d-orbital occuptaion and coordination number of the central metal ion in the following complexes:
[Mn(H2O)6SO4

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188.

Write down the IUPAC name for each of the following complexes and indicate the oxidation state, electronic configuration & coordination number, Also give stereochemistry and magnetic moment of the complex:
K[Cr(H2O)2(C2O4)2]. 3H2O

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189.

Write down the IUPAC name for each of the following complexes and indicate the oxidation state, electronic configuration & coordination number, Also give stereochemistry and magnetic moment of the complex:
CrCl3(py)3


CrCl3(py)3

IUPAC name: Trichloridotripyridinechromium(III) oxidation state +3.
Electronic configuration for d3 =t2g3  c
oordination number =6 .
shape : Octahedral.

Sterochemistry:

Stereochemistry both isomers are optically active. Therefore, a total of 4 isomers exist.

Magnetic moment

 n(n+2)=3(3+2)=15=~4BM



 
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190.

Write down the IUPAC name for each of the following complexes and indicate the oxidation state, electronic configuration & coordination number, Also give stereochemistry and magnetic moment of the complex:
Cs[FeCl4].

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