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 Multiple Choice QuestionsShort Answer Type

201.

Deduce the magnetic behaviour of each of the following:
 (i) [Cr(NH3 )5Cl]2+
(ii) Fe(CO)5 [At. No. Cr = 24, Fe = 26]

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202.

Using valence bond theory predict the geometry and magnetic behaviour of [Cr(NH3)6]3+ ion [Cr = 24].

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203.

Write IUPAC name of [Pt(NH3)2Cl2].

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204.

Using valence bond theory, predict the shape and magnetic character of [Ni(CO)4] [Ni = 28].


Ni(28) has outer electronic configuration 4s23d8. The oxidation state of Ni is zero . Thus electronic configuration is 4s°3d10.



Since there is no any unpaired electron therefore it is diamagnetic in nature and tetrahedral in shape due to sp
3 hybridization.
 
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205.

Give one example of application of coordination compounds in medicine.

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206.

What type of isomerism is exhibited by the following pair:
[Co(NH3)5Br]SO4 and [Co(NH3)SO4] Br
Give a chemical test to distinguish them.

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207.

Write the formula for potassium tri-oxalato chromate(III).

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208.

Give one example of co-ordination compounds useful in biological processes.

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209.

Under the valence bond approach explain the shape and magnetic behaviour of [Ni(NH3)6]2+.[Given At. No. of Ni = 28]

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210.

Explain the following:
Cobalt metal complex is pink when it is octahedral [Co(H2O)6]2+ and it is blue when tetrahedral [CoCl4]2–

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