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 Multiple Choice QuestionsShort Answer Type

201.

Deduce the magnetic behaviour of each of the following:
 (i) [Cr(NH3 )5Cl]2+
(ii) Fe(CO)5 [At. No. Cr = 24, Fe = 26]

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202.

Using valence bond theory predict the geometry and magnetic behaviour of [Cr(NH3)6]3+ ion [Cr = 24].

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203.

Write IUPAC name of [Pt(NH3)2Cl2].

771 Views

204.

Using valence bond theory, predict the shape and magnetic character of [Ni(CO)4] [Ni = 28].

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205.

Give one example of application of coordination compounds in medicine.

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206.

What type of isomerism is exhibited by the following pair:
[Co(NH3)5Br]SO4 and [Co(NH3)SO4] Br
Give a chemical test to distinguish them.

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207.

Write the formula for potassium tri-oxalato chromate(III).

258 Views

208.

Give one example of co-ordination compounds useful in biological processes.

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209.

Under the valence bond approach explain the shape and magnetic behaviour of [Ni(NH3)6]2+.[Given At. No. of Ni = 28]


Ni has an electronic configuration of 4s2,3d8 therefore, Ni2+ has an electronic configuration of 4s0, 3d8. Electrons are always removed from the 4s atomic orbital first. 




Since there are two unpaired electrons, so the species is paramagnetic and since it is sp3d2 hybridization therefore shape is octahedral.


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210.

Explain the following:
Cobalt metal complex is pink when it is octahedral [Co(H2O)6]2+ and it is blue when tetrahedral [CoCl4]2–

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