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 Multiple Choice QuestionsMultiple Choice Questions

331.

Which one of the following complexes shows optical isomerism?

  • cis[Co(en)2Cl2]Cl

  • trans[Co(en)2Cl2]Cl

  • [Co(NH3)4Cl2 ]Cl

  • [Co(NH3)4Cl2 ]Cl

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332.

The number of geometric isomers that can exist for square planar [Pt (Cl) (py) (NH3) (NH2OH)]+ is (py = pyridine)

  • 2

  • 3

  • 4

  • 4

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333.

The Colour of KMnO4 is due to 

  • M → L charge transfer transition

  • d-d transition

  • L →M charge transfer transition

  • L →M charge transfer transition

493 Views

334.

Which of the following compounds will exhibit geometrical isomerism?

  • 1-phenyl-2-butene

  • 3-phenyl-1-butene

  • 2-phenyl-1-butene

  • 2-phenyl-1-butene

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335.

Which of the following compounds is not coloured yellow?

  • Zn2[Fe(CN)6]

  • K3[Co(NO2)6]

  • (NH4)3[As(Mo3O10)4]

  • (NH4)3[As(Mo3O10)4]

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336.

The octahedral complex of a metal ion M3+ with four Monodentate Ligands, L1, L2, L3 and L4 absorb wavelengths in the region of red, green, yellow and blue respectively. The increasing order of ligand strength of the four ligands is

  • L4< L3<L2<L1

  • L1<L3<L2<L4

  • L3<L2<L4<L1

  • L3<L2<L4<L1


B.

L1<L3<L2<L4



λ L1 L2 L3 L4
Absorbed light Red Green Yellow Blue
the wavelength of absorbed light decreases

Therefore, increasing order of energy of wavelengths abosrbed reflects greater extent of crystal - field splitting, hence higher field strength of the ligand.
Energy: Blue(L4)> Green (L2)> Yellow (L3) > Red (L1)
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337.

Which of the following properties are not shown by NO?

  • It is diamagnetic in gaseous state

  • It is a neutral oxide

  • It combines with oxygen to form nitrogen dioxide

  • It combines with oxygen to form nitrogen dioxide

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338.

Which of the following complex species is not expected to exhibit optical isomerism? 

  • [Co(en)3]3+

  • [Co(en)2Cl2]+

  • [Co(NH3)3Cl3]

  • [Co(NH3)3Cl3]

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339.

Which one of the following molecules is expected to exhibit diamagnetic behaviour?

  • C2

  • O2

  • N2

  • N2

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340.

Which among the following will be named as dibromidobis(ethylene diamine)chromium(III) bromide?

  • [Cr(en)3]Br3

  • [Cr(en)2Br2]Br

  • [Cr(en)Br4]-

  • [Cr(en)Br4]-

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