Multiple Choice QuestionsWhich one of the following complexes shows optical isomerism?
cis[Co(en)2Cl2]Cl
trans[Co(en)2Cl2]Cl
[Co(NH3)4Cl2 ]Cl
[Co(NH3)4Cl2 ]Cl
The number of geometric isomers that can exist for square planar [Pt (Cl) (py) (NH3) (NH2OH)]+ is (py = pyridine)
2
3
4
4
The Colour of KMnO4 is due to
M → L charge transfer transition
d-d transition
L →M charge transfer transition
L →M charge transfer transition
Which of the following compounds will exhibit geometrical isomerism?
1-phenyl-2-butene
3-phenyl-1-butene
2-phenyl-1-butene
2-phenyl-1-butene
Which of the following compounds is not coloured yellow?
Zn2[Fe(CN)6]
K3[Co(NO2)6]
(NH4)3[As(Mo3O10)4]
(NH4)3[As(Mo3O10)4]
The octahedral complex of a metal ion M3+ with four Monodentate Ligands, L1, L2, L3 and L4 absorb wavelengths in the region of red, green, yellow and blue respectively. The increasing order of ligand strength of the four ligands is
L4< L3<L2<L1
L1<L3<L2<L4
L3<L2<L4<L1
L3<L2<L4<L1
Which of the following properties are not shown by NO?
It is diamagnetic in gaseous state
It is a neutral oxide
It combines with oxygen to form nitrogen dioxide
It combines with oxygen to form nitrogen dioxide
Which of the following complex species is not expected to exhibit optical isomerism?
[Co(en)3]3+
[Co(en)2Cl2]+
[Co(NH3)3Cl3]
[Co(NH3)3Cl3]
C.
[Co(NH3)3Cl3]
Complexes of the type [MA2(AA2), [M(AA3)] exhibit optical isomerism.
Optical Isomerism is shown by only those complexes which lack elements of symmetry.
In the given complexes, [Co(NH3)3Cl3] shows facial as well as meridional isomerism. But both of the forms contain a plane of symmetry. Thus, only [Co(NH3)3Cl3] complex does not show optical isomerism.
Which one of the following molecules is expected to exhibit diamagnetic behaviour?
C2
O2
N2
N2
Which among the following will be named as dibromidobis(ethylene diamine)chromium(III) bromide?
[Cr(en)3]Br3
[Cr(en)2Br2]Br
[Cr(en)Br4]-
[Cr(en)Br4]-
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