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 Multiple Choice QuestionsMultiple Choice Questions

431.

Coordination number 8 : 8 is of

  • CsCl

  • KCl

  • NaCl

  • ZnS


432.

Which of the following differs in EAN?

  • [Co(NH3)6]Cl3

  • K4[Fe(CN)6]

  • K2[ZnCl4]

  • K2[HgI4]


433.

The pair of coordination compounds [Co(NH3)5Br]SO4 and [Co(NH3)5SO4]Br is an example for

  • geometrical isomerism

  • coordination isomerism

  • structural isomerism

  • ionisation isomerism


434.

The correct nomenclature Fe4[Fe(CN)6]3

  • ferroso ferric cyanide

  • ferric- ferrous hexacyanate

  • iron(III) hexacyanoferrate(II)

  • hexa cyanoferrate(III-II)


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435.

For an ionic crystal of the general formula AX and coordination number is 6, the value of radius ratio will be

  • greater than 0.73

  • in between 0.73 and 0.41

  • in between 0.41 and 0.22

  • less than 0.22


436.

Number of ions for the complex [Co(NH3)4Cl]Cl2 shown by the conductivity measurement, is

  • 2

  • 4

  • 3

  • 1


437.

Coordination number of Fe in the complexes [Fe(CN)6]4-, [FeCN)6]3- and [FeCl4]- would be respectively

  • 6, 3, 4

  • 6, 6, 4

  • 2, 3, 3

  • 6, 4, 6


438.

[(C6H5)2Pd(NCS)2] and [(C6H5)2Pd(SCN)2] are

  • bond isomeric

  • coordinated isomeric

  • ionic isomeric

  • geometrical isomeric


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439.

In which of the following complex compounds the oxidation number of the metal is zero?

  • [Pt(NH3)2Cl2]

  • [Cr(CO)6]

  • [Cr(NH3)3Cl3]

  • [Cr(en)2Cl2]


B.

[Cr(CO)6]

The oxidation number of Cr, is zero in the [Cr(CO)6] complex because CO is a neutral ligand.


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440.

Formula of hexaaqua manganese (II) phosphate is

  • [Mn(H2O)]6PO4

  • [Mn(H2O)6]3PO4

  • [Mn(H2O)6]3(PO4)2

  • [Mn(H2O)6](PO4)3


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