The IUPAC name of the complex ion formed when gold dissolves in a

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471.

The IUPAC name of the complex ion formed when gold dissolves in aqua-regia is

  • tetrachloridoaurate (III)

  • tetrachloridoaurate (I)

  • tetrachloridoaurate (II)

  • dichloridoaurate (III)


A.

tetrachloridoaurate (III)

Aqua-regia is a solution containing conc. HCl and conc. HNO3 in the ratio 3 : 1. It dissolves noble metals like Au, Pt, etc.

HNO3 + 3HCl → 2H2O + 2Cl + NOCl

      Au + 3Cl → AuCl3

  AuCl3 + HCl → 4AuCl4Tetrachloridoaurate (III)


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472.

Which of the following will be able to show geometrical isomerism?

  • MA3B - Square planar

  • MA2B2 - tetrahedral

  • MABCD- saquare planar

  • MABCD- tetrahedral


473.

The complex formed when Al2O3 is leached from bauxite using conc. NaOH solution is,

  • Na[Al(OH)4]

  • NaAl2O4

  • Na[Al(OH)3]

  • Na2AlO2


474.

The number of isomers possible for the octahedral complex [CoCl2(en)(NH3)2]+ is

  • two

  • three

  • no isomer

  • four isomers


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475.

The complex ion having minimum magnitude of Δ° (CFSE) is

  • [Cr(CN)6]3-

  • [Co(CN3)6]3+

  • [Co(Cl)6]3+

  • [Cr(H2O)6]3+


476.

As per IUPAC norms, the name of the complex [Co(en)2(ONO)Cl]Cl is

  • chlorido bis (ethane-1, 2-diamine) nitro-O-cobalt (III) chloride

  • chlorido bis (ethylenediamine) nitro-O-cobalt (III) chloride

  • chlorido di (ethylenediamine) nitrocobalt (III) chloride

  • chloro ethylenediaminenitr-O-cobalt (III) chloride


477.

Square planar complex of the type MAXBL (where A, B,X and L) are unidenate ligands) shows following set of isomers.

  • two cis and one trans

  • two trans and one cis

  • two cis and two trans

  • three cis and one trans


478.

The formula of potash alum is :

  • K2SO4.Al2(SO4)3.24H2O

  • K2SO4.Al2(SO4)3.18H2O

  • K2SO4.(NH4)2SO4.18H2O

  • Na2SO4.Al2(SO4)3.24H2O


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479.

[EDTA]4- is a 

  • monodentate ligand

  • bidentate ligand

  • quadridentate ligand

  • hexadentate ligand


480.

According to crystal field theory, the M-L bond in a complex is

  • partially covalent

  • purely ionic

  • purely covalent

  • purely coordinate


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