The pair in which both species have same magnetic moment (spin on

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 Multiple Choice QuestionsMultiple Choice Questions

591.

Assertion:

 is named as tetrakis (ethylene-diammine) μ-hydroxo-m-imido dicobalt (III) ion.

Reason : In naming polynuclear complexes i.e., containing two or more metal atoms joined by bridging ligands, the word μ is added with hyphen before the name of such ligands.

  • If both assertion and reason are true and reason is the correct explanation of assertion.

  • If both assertion and reason are true but reason is not the correct explanation of assertion.

  • If assertion is true but reason is false.

  • If both assertion and reason are false.


592.

Which of the following is considered as an anticancer species?


593.

Assertion : Al forms [AlF6]3- but B does not form [BF6]3-.

Reason : B does not react with fluorine.

  • If both assertion and reason are true and reason is the correct explanation of assertion

  • If both assertion and reason are true but reason is not the correct explanation of assertion

  • If assertion is true but reason is false

  • If both assertion and reason are false


594.

Which of the following metal ions will form complexes with the same magnetic moment and geometry irrespective of the nature of ligands?

  • Ni2+

  • Fe2+

  • Cu2+

  • Co2+


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595.

Wavelength of red light is absorbed by the complex

  • [Cu(CN)4]2-

  • [Cu(NH3)4]2+

  • CuSO4

  • Cu(CN)2


596.

In the change[Cu(H2O)6F]2+ HCl [CuCl(H2O)5]+, the colour changes from

  • blue to green

  • blue to pink

  • pink to green

  • pink to blue


597.

Assertion : In high spin situation, configuration
of d5 ions will be t2g3, eg2.

Reason : In high spin situation, pairing energy is less than crystal field energy.

  • If both assertion and reason are true and reason is the correct explanation of assertion.

  • If both assertion and reason are true but reason is not the correct explanation of assertion.

  • If assertion is true but reason is false.

  • If both assertion and reason are false.


598.

Which of the following does not contain any coordinate bond?

  • H3O+

  • BF4-

  • HF2-

  • NH4+


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599.

The pair in which both species have same magnetic moment (spin only value) is

  • [Cr(H2O)6]2+,[CoCl4]2+

  • [Cr(H2O)6]2+,[Fe(H2O)6]2+

  • [Mn(H2O)6]2+, [Cr(H2O)6]2+

  • [CoCl4]2-, [Fe(H2O)6]2+


B.

[Cr(H2O)6]2+,[Fe(H2O)6]2+

Spin only magnetic moment, μ=n(n+2) where n= number of unpaired electrons. Number of unpaired electrons in Cr2+ ([Ar] 3d4) is 4, in Co2+ ([Ar] 3d7) is 3, Fe2+([Ar]3d6) is 4, in Mn2+([Ar]3d5) is 5.


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600.

Which gives nucleophilic addition most easily :

  • CH3CHO

  • CH3CH2CHO

  • (CH3)2CHCHO

  • HCHO


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