Which one ofthe following forms with an excess of CN- (cyanide) a

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 Multiple Choice QuestionsMultiple Choice Questions

601.

The colour imparted by Co(II) compounds to glass is

  • green

  • deep-blue

  • yellow

  • red


602.

The number of possible isomers of an octahedral complex[Co(C2O4)2(NH3)2].

 

  • 1

  • 2

  • 3

  • 4


603.

The ligands in anti-cancer drug cisplatin are

  • NH3, Cl

  • NH3, H2O

  • Cl, H2O

  • NO, Cl


604.

The magnetic moment of K3[Fe(CN)6]  is found to be 1.7 BM .How many unpaired electron (s) is/are present per molecule ?

  • 1

  • 2

  • 3

  • 4


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605.

In [Ag(CN)2]-, the number of π bonds is

  • 2

  • 3

  • 4

  • 6


606.

An aqueous solution of CoCl2 on addition of excess of concentrated HCl turns blue due to formation of

  • [Co(H2O)4Cl2]

  • [Co(H2O)2Cl4]2-

  • [CoCl4]2-

  • [Co(H2O)2Cl2]


607.

In which of the following pairs both the complexes show optical isomerism?

  • cis-[Cr(C2O4)2Cl2]3-, cis-[Co(NH3)4Cl2]

  • [Co(en)3]Cl3cis-[Co(en)2Cl2]Cl

  • [PtCl(dien)]Cl, [NiCl2Br2]2-

  • [Co(NO3)3(NH3)3], cis-[Pt(en)2Cl2]


608.

The correct order for the wavelength of absorption in the visible region is

  • [Ni(NO2)6]4- < [Ni(NH3)6]2+ < [Ni(H2O)6]2+

  • [Ni(NO2)6]4- < [Ni(H2O)6]2+ < [Ni(NH3)6]2+

  • [Ni(H2O)6]2+ < [Ni(NH3)6]2+ < [Ni(NO2)6]4-

  • [Ni(NH3)6]2+ < [Ni(H2O)6]2+ < [Ni(NO2)6]4-


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609.

Which one ofthe following forms with an excess of CN- (cyanide) a complex having coordination number two?

  • Cu+

  • Ag+

  • Ni2+

  • Fe2+


B.

Ag+

Ag- of AgCN is soluble in excess cyanide ion to form [Ag(CN)2]- complex.


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610.

Which of the following is not considered as an organometallic compound?

  • cis-Platin

  • Ferrocene

  • Zeise's salt

  • Grignard reagent


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