Given the standard electrode potentials: K+/K = – 2.93 V Ag+/Ag = 0.80V Hg2+/Hg = 0.79 V Mg2+/Mg = –2.37 V Cr3+/Cr = –0.74 V. Arrange these metals in their increasing order of reducing power.
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72.What is the efficiency of fuel cell? What is the use of fuel cell?
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73.Write the correct representation of cell: 2Cr(s) + 3Cd2+ (aq) → 2Cr3+ (aq) + 3Cd(s)
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74.What is the relationship between equivalent conductance and specific conductance?
75.What is the role of the salt bridge in a voltaic cell?
Answer:
A salt bridge allows the flow of ions to maintain a balance in charge between the oxidation and reduction vessels while keeping the contents of each separate. With the charge difference balanced, electrons can flow once again, and the reduction and oxidation reactions can proceed.
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76.What is the effect of dilution on equivalent conductance of solution?
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77.How is molar conductivity is related to molarity of electrolyte solutions?
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78.For the electrochemical reaction: Zn2+(aq) + Cu(s) → Zn(s) + Cu2+(aq) [E°cell = – 1.10 V] What does the negative value of E°cell indicate?
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79.Why is not possible to determine for weak electrolytes by extrapolation?
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80.What is the use of platinum foil in the hydrogen electrode?