Calculate the molar conductivity at infinite dilution of acetic acid from the following data:
Λ∞m (HCl) = 426 ohm–1 cm2 mol–1, Λ∞m CH3COONa = 91 ohm–1 cm2 mol–1 and Λ∞m(NaCl) = 126 ohm–1 cm2 mol–1.
We have given
E°Ni2+/Ni = -0.25 V
E°Cu2+/Cu = + 0.34 V,
Ecell0 =
= 0.34-(-0.25)
= 0.34+0.25 =0.59
R = 8.314 J K–1 mol–1
F = 96500 C mol–1.
T=25celcius =273+25 =298 Kelvin
n= 2
= Antilog[19.956]
Ans. 9.07 x 1019
Consider the cell Zn/Zn2+ (aq) (1.0 M) || Cu2+ (aq) (0.1 M) | Cu The standard reaction potentials are + 0.35 V for 2e– + Cu2+ (aq) → Cu and – 0.763 V for 2e– + Zn2+ (aq) → Zn
(i) Write down the cell reaction.
(ii) Calculate the emf of the cell.
(iii) Is the cell reaction spontaneous or not?
The standard reduction potential of the reaction at 25°C
2H2O + 2e– H2(g) + 2OH– is – 0.8277 V
Calculate equilibrium constant for the reaction
at