Calculate the molar conductivity at infinite dilution of acetic acid from the following data:
Λ∞m (HCl) = 426 ohm–1 cm2 mol–1, Λ∞m CH3COONa = 91 ohm–1 cm2 mol–1 and Λ∞m(NaCl) = 126 ohm–1 cm2 mol–1.
Consider the cell Zn/Zn2+ (aq) (1.0 M) || Cu2+ (aq) (0.1 M) | Cu The standard reaction potentials are + 0.35 V for 2e– + Cu2+ (aq) → Cu and – 0.763 V for 2e– + Zn2+ (aq) → Zn
(i) Write down the cell reaction.
(ii) Calculate the emf of the cell.
(iii) Is the cell reaction spontaneous or not?
The standard reduction potential of the reaction at 25°C
2H2O + 2e– H2(g) + 2OH– is – 0.8277 V
Calculate equilibrium constant for the reaction
at
We ave given that
R = 1500 Ω
K = 1.46 x 10–4 Ω–1 cm–1
Cell constant = K x R
= 1.46 x 10–4 x 1500 = 0.219