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 Multiple Choice QuestionsMultiple Choice Questions

441.

The standard electrode potentials of Ag+/Ag is +0.80V and Cu+/Cu is +0.34 V. These electrodes are connected through a salt bridge and if:

  • copper electrode acts as a cathode then E° cell is +0.46 V

  • silver electrode acts as anode then E° cell is -0.34 V

  • copper electrode acts as anode then E° cell is +0.46 V

  • silver electrode acts as a cathode then E° cell is -0.34 V


442.

If three Faradays of electricity is passed through the solutions of AgNO3, CusO4 and AuCl3, the molar ratio of the cations deposited at the cathodes will be :

  • 1 : 1 : 1

  • 1 : 2 : 3

  • 3 : 2 : 1

  • 6 : 3 : 2


443.

ECu° - 0.34 V; EZn° = 0.76 V. A Daniel cell contains 0.1 M ZnSO4 solution and 0.01M CuSO4 solution at its electrodes. EMF of the cell is:

  • 1.10 V

  • 1.04 V

  • 1.16 V

  • 1.07 V


444.

When electric current is passed through an ionic hydride in molten state :

  • hydrogen is liberated at anode

  • hydrogen is liberated at cathode

  • no change takes place

  • hydride for migrates towards cathode


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445.

What is potential of platinum wire dipped into a solution of 0.1 M in Sn2+ and 0.01 M in Sn4+ ?

  • E° + 0.059

  • E° + 0.0592

  • E° - 0.059


446.

Zn(s) | Zn2+(aq)|| Cu2+(aq) | Cu(s) is :

(anode)                        (cathode)

  • Weston cell

  • Daniel cell

  • Faraday cell

  • Standard cell


447.

Copper sulphate solution does not react with

  • Zinc

  • Iron

  • Silver

  • All of these


448.

When 1 F of electricity is passed through acidulated water, O2 evolved is

  • 11.2 dm3

  • 5.6 dm3

  • 22.4 dm3

  • 1.0 dm3


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449.

Standard electrode potential of cell H2 | H+||Ag+| Ag is

  • 0.8 V

  • -0.8 V

  • -1.2 V

  • 1.2 V


A.

0.8 V

Ecell = EC-EAGiven,EAg+/Ag° = 0.80 VHydrogen is anode and silver is cathode. ECell= EC-EA        = 0.80 -0     (EH+/H°=0)


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450.

The oxidation potential values of A, B, C and D are -0.03 V, +0.108 V, -0.07 V and +0.1 V respectively. The non-spontaneous cell reaction takes place between

  • A and B

  • Band D

  • D and A

  • B and C


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