The compounds formed at anode in the electrolysis of an aqueous s

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 Multiple Choice QuestionsMultiple Choice Questions

631.

Electrolysis of fused NaCl will give

  • Na

  • NaOH

  • NaClO

  • NaClO3


632.

How long it will take to deposit 1.0 g of chromium when a current of 1.25 A flows through a solution of chromium (III) sulphate ? (Molar mass of Cr = 52)

  • 1.24 min

  • 1.24 h

  • 1.24 s

  • None of these


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633.

The compounds formed at anode in the electrolysis of an aqueous solution of potassium acetate, are

  • C2H6 and CO2

  • C2H4 and CO2

  • CH4 and H2

  • CH4 and CO2


A.

C2H6 and CO2

The compounds formed at anode in the electrolysis of an aqueous solution of potassium acetate, are C2H6 and CO2.

Eg, Kolbe's electrolysis

2CH3COOK electrolysis 2CH3COO- + 2K+

At cathode - 

2K+ + 2e-  2K

At anode - 

2CH3COO-  2CH3COO +2e-

                           -2CO2

                         2CH3

                            

                         C2H6


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634.

What is the electrode potential (in V) of the following electrode at 25°C ?

Ni2+ (0.1 M) | Ni(s)

(Standard reaction potential of Ni2+ | Ni is -0.25V, 2.303 RTF = 0.06)

  • -0.28V

  • -0.34V

  • -0.82V

  • -0.22V


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635.

EMF or hydrogen electrode in terms of pH at 1 atm pressure is

  • EH2 = RTFpH

  • EH2 = RTF1pH

  • EH2 = 2.303 RTFpH

  • EH2 = -0.0591 pH


636.

Assuming that constant current is delivered. How many kW-h of electricity can be produced by the reaction of 1.0 mole Zn with Cu ion in a Daniel cell in which all the concentration remains 1.00 M.

(Given EGiven E°Zn/Zn+=0.76=0.76V),

  • 0.069 kW-h

  • 0.074 kW-h

  • 0.080 kW-h

  • 0.059 kW-h


637.

What amount of Cl2 gas liberated at anode, if 1 ampere current is passed for 30 minute from NaCl solution ?

  • 0.66 mol

  • 0.33 mol

  • 0.66 g

  • 0.33 g


638.

For the given,Sn Sn2+ (0.1 M)  +  2e(Given ESn/Sn2+0= 0.136 V)The electrode potential of the cell at 25° C is:

  • 0.165 V

  • 0750 V

  • 0.421 V

  • 0.012 V


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639.

A 35% solution LiCl was electrolysed by using a 2.5A current for 0.8h.Assuming thecurrent efficiency of 90%. The mass of LiOHproduced at the end of electrolysis.
[Atomic mass of Li=7] is:

  • 1.61 g

  • 2.71 g

  • 4.02 g

  • 3.70 g


640.

Which of the following formula is applicable for weak electrolyte:

  • α=λmλm

  • Ka=2(1-α)

  • Ka=m2λm(λm-λm)

  • All of these


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