Important Questions of Equilibrium Chemistry | Zigya

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 Multiple Choice QuestionsShort Answer Type

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291.

Calculate the degree of hydrolysis of 0.015 M solution of NH4Cl. Given Kb for NH4OH is 1·8 × 10–5, Kw = 10–14at 25°C.

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 Multiple Choice QuestionsLong Answer Type

292.

Explain the terms: buffer solution and buffer capacity.

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293.

Show with an example how buffer solution resists the action of acid or base towards change in pH.
Or
Discuss the buffer action of:
(i) acidic buffer
(ii) basic buffer.

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294. How will you explain buffer action of aqueous solution of ammonium acetate?
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295.

Calculate the pH of:
(i) an acidic buffer mixture 
(ii) a basic buffer mixture.
Or
Derive Henderson’s equation for an acidic and basic buffer mixture.
Or
Derive the following equation for the pH of an acidic buffer:
pH space equals space pK subscript straight a space plus space log space fraction numerator open vertical bar Salt close vertical bar over denominator open vertical bar Acid close vertical bar end fraction

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 Multiple Choice QuestionsShort Answer Type

296. Calculate the pH value of a solution obtained by mixing 0·083 moles of acetic acid and 0·091 moles of sodium acetate and making the volume 500 ml. Ka for acetic acid is 1·75 × 10–5.
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 Multiple Choice QuestionsLong Answer Type

297. Calculate the pH of a solution obtained by mixing 6·0g of acetic acid and 12·30g of sodium acetate and making the volume of solution to 500 ml. Ka for acetic acid is 1·8 × 10–5
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298. Determine the pH of a solution obtained by mixing equal volumes of 0·015N NH4OH and 0·15N NH4NO3 solutions. (Kb for NH4OH is 1·8 × 10–5).
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299.

Describe Ostwald’s theory of acid-base indicators.
Or
How does Ostwald’s theory explain the colour change of:
(i) Phenolphthalein
(ii) Methyl orange in acid-base titrations?

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 Multiple Choice QuestionsShort Answer Type

300.

How does the concept of solubility product help in finding out the solubility of sparingly soluble salts?

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