What do you understand by conjugate acid base pairs? Give exampl

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 Multiple Choice QuestionsShort Answer Type

201. What are the limitations of Arrhenius theory of acid and bases?
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202. Define neutralisation according to Arrhenius concept.
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 Multiple Choice QuestionsLong Answer Type

203.

Discuss the Lowry Bronsted concept of acids and bases.
Or
Discuss the protonic concept of acids and bases.

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204. What do you understand by conjugate acid base pairs? Give examples.


A species formed by adding a proton to Bronsted base is called conjugate acid and a species formed by losing a proton from Bronsted acid is called conjugate base. 



Thus, every acid has its conjugate base and every base has its conjugate acid. Consider a reaction between HCl and H2O.



In the forward reaction, HCl donates a proton to water.

∴  HCl is an acid and H2O is a base.
In the backward reaction, H3O+ ion donates a proton to Cl ion.

∴    H3O+ is an acid and Cl is a base.
Thus Cl ion is a conjugate base of HCl and H3Ois the conjugate acid of base H2O. Such pairs of substances which differ from one another by a proton are known as conjugate acid-base pairs. Thus any acid-base reaction really involves two acids and two bases, forming conjugate pairs.



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 Multiple Choice QuestionsShort Answer Type

205. State the formula and name of the conjugate base of each of the following acid:
left parenthesis straight i right parenthesis space straight H subscript 3 straight O to the power of plus space space space space space space space space space left parenthesis ii right parenthesis space space space HSO subscript 4 superscript minus
left parenthesis iii right parenthesis space NH subscript 4 superscript minus space space space space space space space space space left parenthesis iv right parenthesis space space HF
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206. State the formula and name of the conjugate base of the following acids:
(i)CH3COOH              (ii) CH3NH3+  
(iii)H3PO4                       left parenthesis iv right parenthesis space straight H subscript 2 PO subscript 4 superscript minus
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207. State the formula and name of conjugate acid of the following bases:
(i) OH               left parenthesis ii right parenthesis space HPO subscript 4 superscript 2 minus end superscript
left parenthesis iii right parenthesis space straight H subscript 2 PO subscript 4 superscript minus space space space space space space space space space space left parenthesis iv right parenthesis space space CH subscript 3 NH subscript 2

 

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208.

State the formula and name of conjugate acid of the following bases:
(i) CO subscript 3 superscript 2 minus end superscript                                 (ii) NH3
(iii) CH3COO                         (iv) HS

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209. What is meant by the conjugate acid-base pair? Find the conjugate acid/base for the following species:
HNO subscript 2 comma space space CN to the power of minus comma space space space HClO subscript 4 comma space space space straight F to the power of minus comma space space space OH to the power of minus comma space space CO subscript 3 superscript 2 minus end superscript space and space straight S to the power of 2 minus end exponent.
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210. What will be the conjugate bases for the Bronsted acids : HF, H2SO4 and HCO-3?
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