Trying to find the right answer to this..

(i) It fails to explain the reaction between acidic oxides (SO 2 , SO 3 etc.) and basic oxides (BaO, CaO, Na 2 O etc.) because, in such reactions, no proton transfer occurs. (ii) It fails to recognise the acidic character of FeCl 3 , AlCl 3 BF 3 etc.

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Equilibrium

Short Answer Type

211.

Write the conjugate acids for the following Bronsted bases: $NH subscript 2 superscript minus$ , NH₃ and HCOO^–.

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212.

The species: $straight H subscript 2 straight O comma space space HCO subscript 3 superscript minus comma space space space HSO subscript 4 superscript minus space and space NH subscript 3$ can act both as Bronsted acids and bases. For each case give the corresponding conjugate acid and base.

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213.

Identify the acids and bases in the following equilibrium reactions:

$straight i right parenthesis space HCl plus space straight H subscript 2 straight O space rightwards harpoon over leftwards harpoon space straight H subscript 3 straight O to the power of plus space plus Cl to the power of minus ii right parenthesis space HNO subscript 3 space plus straight H subscript 2 straight O space rightwards harpoon over leftwards harpoon space straight H subscript 3 straight O to the power of plus space plus NO subscript 3 superscript minus iii right parenthesis space CO subscript 3 superscript 2 minus end superscript space plus straight H subscript 2 straight O space rightwards harpoon over leftwards harpoon space OH to the power of minus space plus HCO subscript 3 superscript minus$

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214.

Select conjugate acid-base pairs from the following equations?

$straight i right parenthesis space NH subscript 3 space plus straight H subscript 2 straight O space rightwards harpoon over leftwards harpoon space NH subscript 4 superscript plus space plus OH to the power of minus ii right parenthesis space straight H subscript 2 SO subscript 4 space plus straight H subscript 2 straight O space rightwards harpoon over leftwards harpoon space straight H subscript 3 straight O to the power of plus space plus HSO subscript 4 superscript minus iii right parenthesis space straight H subscript 2 PO subscript 4 superscript minus space plus straight H subscript 2 straight O space rightwards harpoon over leftwards harpoon space straight H subscript 3 straight O to the power of plus space plus HPO subscript 4 superscript 2 minus end superscript$

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215. Describe how water behaves both as an acid or a base.

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216. Comment on the statement: Strong acid has a weak conjugate base and vice-versa.

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Long Answer Type

217.

All Arrhenius acids are Bronsted acids while all Arrhenius bases arc not Bronsted bases. Discuss.

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Short Answer Type

218.
What are the limitations (drawbacks) of Bronsted-Lowry concept of acids and bases?

(i) It fails to explain the reaction between acidic oxides (SO₂, SO₃ etc.) and basic oxides (BaO, CaO, Na₂O etc.) because, in such reactions, no proton transfer occurs.

(ii) It fails to recognise the acidic character of FeCl₃, AlCl₃ BF₃ etc.

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